ChemicalBook--->CAS DataBase List--->19978-61-1

19978-61-1

19978-61-1 Structure

19978-61-1 Structure
IdentificationMore
[Name]

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
[CAS]

19978-61-1
[Synonyms]

[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLOROPALLADIUM(II)
1,2-[BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(II) CHLORIDE
[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(II) DICHLORIDE
DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(II)
DICHLORO[BIS(1,2-DIPHENYLPHOSPHINO)ETHANE]PALLADIUM(II)
Dichloro[1,2-bis(diphenylphosphino)ethanepalladiu
Dichloro (1,2-Bis (diphenylphosphino)ethane dichlorpalladium (II))
Dichloro(1,2-bis(diphenylphosphino)ethane)palladium(II),98%
DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE PALLADIUM()]
Dichloro[bis(1,2-diphenylphosphino)ethane]palladium(II), Pd 18.5%
Dichloro[1,2-bis(diphenylphosphano)ethane]palladium(II)
[EINECS(EC#)]

625-508-5
[Molecular Formula]

C26H24Cl2P2Pd
[MDL Number]

MFCD00015702
[Molecular Weight]

575.74
[MOL File]

19978-61-1.mol
Chemical PropertiesBack Directory
[Appearance]

orange powder
[Melting point ]

360 °C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[color ]

off-white
[Water Solubility ]

insoluble
[Sensitive ]

Moisture sensitive
[InChI]

InChI=1S/C26H24P2.2ClH.Pd/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
[InChIKey]

LDJXFZUGZASGIW-UHFFFAOYSA-L
[SMILES]

C(P(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1.[Pd](Cl)Cl
[CAS DataBase Reference]

19978-61-1(CAS DataBase Reference)
[Storage Precautions]

Store under nitrogen;Moisture sensitive;Air sensitive
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[HS Code ]

28439000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Toluene-->Acetonitrile-->Triphenylphosphine-->Lithium-->Palladium chloride
Hazard InformationBack Directory
[Chemical Properties]

orange powder
[Uses]

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) is a precatalyst used in the production of acrylic acid sodium salt via coupling of CO2 with ethene.
suzuki reaction.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
[Precautions]

This palladium catalyst, also known as [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), presents as a very pale yellow to yellow crystalline powder. Store under inert gas, at ambient temperatures and protected from moisture. This substance is moisture sensitive. [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride is incompatible with oxidizing agents. This chemical is harmful if swallowed, in contact with skin or if inhaled. It causes skin irritation as well as serious eye irritation.?
Spectrum DetailBack Directory
[Spectrum Detail]

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)(19978-61-1)Raman
[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)(19978-61-1)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II), 98%(19978-61-1)
[Alfa Aesar]

Dichloro[bis(1,2-diphenylphosphino)ethane]palladium(II), Pd 18.5%(19978-61-1)
[Sigma Aldrich]

19978-61-1(sigmaaldrich)
[TCI AMERICA]

[1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride,>98.0%(T)(19978-61-1)
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