| Identification | Back Directory | [Name]
Bis(2,4-pentanediono)nickel | [CAS]
3264-82-2 | [Synonyms]
Ni(acac)2
Acetylacetonenickel
Ni(acac)2
NICKEL PENTANEDIONATE
NICKEL ACETYLACETONATE
Acetylacetonato nickel
Acetylacetonate nickel
Nickel(II) acetylaceton
Nickel diacetylacetonate
nickelousacetylacetonate
BIS(ACETYLACETONATO)(II)
bis(acetylacetone)nickel
Nickel acetonylacetonate
NICKEL 2,4-PENTANEDIONATE
acetylacetonatonickel(ii)
Nickelous acetylacetonate
Nickel(Ⅱ) acetylacetonate
Nickel acetylacetonate,96%
Nickel (II) pentanedionate
NICKEL(II) ACETYLACETONATE
Nickel(2+) acetylacetonate
nickelbis(acetylacetonate)
Bis(acetylacetonate)nickel
Bis(acetylacetonato)nickel
Nickel bis(acetylacetonate)
BIS(2,4-PENTANEDIONO)NICKEL
Nickelous diacetylacetonzte
NICKEL ACETYLACETONATE (OUS)
NICKEL(II) 2,4-PENTANEDIONATE
nickelbis(2,4-pentanedionate)
Bis(2,4-pentanedionato)nickel
acetylacetone nickel(ii) salt
nickel diaqua acetylacetonate
Nickelous diacetyl acetonate
Nickel bis(2,4-pentanedionate)
BIS(ACETYLACETONATO)NICKEL(II)
Nickel(II) acetylacetonate 95%
Nickel acetylacetonate, 96% 5GR
Nickel acetylacetonate, 96% 25GR
BIS(2,4-PENTANEDIONATO)NICKEL(2)
Nickel, bis(2,4-pentanedionato)-
2,4-pentanedione,nickel(ii)deriv.
BIS(2,4-PENTANEDIONATO) NICKEL(II)
Ni(II) Acetylacetone complex (1:2)
Nickel pentanedionate hydrate, 95%
bis(pentane-2,4-dionato-O,O')nickel
NICKEL(II) PENTANEDIONATE, ANHYDROUS
Nickel 2,4-Pentanedionate, Anhydrous
ACETYLACETONE, NICKEL(II) DERIVATIVE
"Nickel(II) 2,4-pentanedionate/ 98+%"
nickel(II) (Z)-4-oxopent-2-en-2-olate
Nickel(II) acetylacetonate, anhydrous
Nickel(II)bis(4-hydroxy-2-pentanolate)
Bis(2,4-pentanedionato)nickel(II)
NICKEL(II) ACETYLACETONATE, TECH., 90%
Nickel acetylacetonate 10% PPG solution
2,4-PENTANEDIONE, NICKEL(II) DERIVATIVE
NICKEL(II) ACETYLACETONATE FOR SYNTHESIS
nickel(ii) 2,4-pentanedionate, anhydrous
4-pentanedionato-o,o’)-bis((sp-4-1)-nicke
bis(2,4-pentanedionato-o,o’)-nicke(sp-4-1)
Nickel(II)acetylacetonate,anhydrous,min.95%
(SP-4-1)-Bis(2,4-pentanedionato-kO,kO')nickel
NICKEL II 2,4-PENTANEDIONATE TRIMERIC COMPOUND
bis(2,4-pentanedionato-κO,κO’)-,(SP-4-1)-Nickel
Nickel(II) acetylacetonate, anhydrous, min. 95%
Nickel, bis(2,4-pentanedionato-O,O')-, (SP-4-1)-
Nickel, bis(2,4-pentanedionato-kO,kO')-, (SP-4-1)-
2,4-Pentanedione nickel(II) derivative, Ni(acac)2
Acetylacetone Nickel(II) Salt
Nickel(II) Acetylacetonate
Nickel, bis(2,4-pentanedionato-.kappa.O,.kappa.O)-, (SP-4-1)-
Nickel(II) acetylacetonate,2,4-Pentanedione nickel(II) derivative, Ni(acac)2
Bis(acetylacetonato)nickel(II)hydrate~Bis(2,4-pentanedionato)nickel(II)hydrate~Nickel(II)2,4-pentanedionatehydrate
Bis(acetylacetonato)nickel(II) hydrate~Bis(2,4-pentanedionato)nickel(II) hydrate~Nickel(II) 2,4-pentanedionate hydrate | [EINECS(EC#)]
221-875-7 | [Molecular Formula]
C10H14NiO4 | [MDL Number]
MFCD00000024 | [MOL File]
3264-82-2.mol | [Molecular Weight]
256.91 |
| Chemical Properties | Back Directory | [Appearance]
light green powder | [Melting point ]
230 °C (dec.)(lit.)
| [Boiling point ]
220 °C (11 mmHg)
| [density ]
0,145 g/cm3 | [vapor pressure ]
2.7 hPa (110 °C) | [refractive index ]
1.57-1.64 | [Fp ]
>200°C | [storage temp. ]
Store below +30°C. | [solubility ]
4.8g/l | [form ]
Liquid | [color ]
Clear pale yellow | [Specific Gravity]
1.455 | [Water Solubility ]
soluble | [Hydrolytic Sensitivity]
0: forms stable aqueous solutions | [Sensitive ]
Hygroscopic | [Merck ]
14,6500 | [BRN ]
4157970 | [Exposure limits]
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 | [Stability:]
hygroscopic | [InChIKey]
YAGMVFMEBGIOTO-FGSKAQBVSA-M | [LogP]
0.4 at 20℃ | [Uses]
Catalyst for organic reactions. | [CAS DataBase Reference]
3264-82-2 | [NIST Chemistry Reference]
Nickel acetylacetonate(3264-82-2) | [EPA Substance Registry System]
Nickel, bis(2,4-pentanedionato-.kappa. O,.kappa.O')-, (SP-4-1)-(3264-82-2) |
| Hazard Information | Back Directory | [Chemical Properties]
light green powder | [Uses]
Catalyst. | [Purification Methods]
Wash the green solid with H2O, dry it in a vacuum desiccator and recrystallise it from MeOH. [Charles & Pawlikowski J Phys Chem 62 440 1958.] The complex can be conveniently dehydrated by azeotropic distillation with toluene, and the crystals may be isolated by concentrating the toluene solution. [Wilkinson et al. J Am Chem Soc 76 1970 1954, Beilstein 1 IV 3677.] | [Flammability and Explosibility]
Notclassified | [reaction suitability]
core: nickel
reagent type: catalyst | [Safety Profile]
Confirmed human carcinogen. Poison by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating fumes. |
| Questions And Answer | Back Directory | [Physical Properties]
Emerald-green crystals; orthorhombic structure; density 1.455 g/cm3 at 17°C; melts at 230°C; soluble in water, alcohol, chloroform, benzene and toluene; insoluble in ether.
| [Uses]
Bis(2,4-pentanediono)nickel is used as a catalyst in hydrogenation and other organic reactions.
| [Preparation]
Nickel acetylacetonate is prepared by the reaction of acetylacetone with nickel chloride hexahydrate or nickel hydroxide, followed by crystallization:
2CH3C(=O)CH2C(=O)CH3 + Ni(OH)2 → Ni(CH3C(=O)CHC(=O)CH3)2 + 2H2O
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