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33008-06-9

33008-06-9 Structure

33008-06-9 Structure
IdentificationMore
[Name]

DANSYL HYDRAZINE
[CAS]

33008-06-9
[Synonyms]

1-DIMETHYLAMINOPHTHALENE-5-SULPHONYL HYDRAZINE
5-(DIMETHYLAMINO)-1-NAPHTHALENESULFONIC HYDRAZIDE
5-[DIMETHYLAMINO]NAPHTHALENE-1-SULFONHYDRAZIDE
5-DIMETHYLAMINONAPHTHALENE-1-SULFONOHYDRAZIDE
5-DIMETHYLAMINONAPHTHALENE-1-SULFONYL HYDRAZINE
DANSYL HYDRAZIDE
DANSYL HYDRAZINE
TIMTEC-BB SBB009944
5-Dimethylaminonaphthalene-1-sulfonyl hydrazine (dansyl hydrazine)
Dansylhydrazine~5-Dimethylamino-1-naphthalenesulphonyl hydrazide
5-dimethylaminonaphthalene-1-sulphonohydrazide
DANSYLHYDRAZINE CRYSTALLINE
DANSYLHYDRAZINE, FOR FLUORESCENCE
5-Dimethylamino-1-naphthalenesulfonylhydrazide
Dansylhydrazine=Dansylhydrazide
Dansyl Hydrazine [for HPLC Labeling]
5-(Dimethylamino)-1-naphthalenesulfonic hydrazide, 5-(Dimethylamino)naphthalene-1-sulfonohydrazide
5-Dimethylaminonaphthalene-1-sulfonic acid hydrazide
[EINECS(EC#)]

251-337-7
[Molecular Formula]

C12H15N3O2S
[MDL Number]

MFCD00003986
[Molecular Weight]

265.33
[MOL File]

33008-06-9.mol
Chemical PropertiesBack Directory
[Melting point ]

126-130 °C (lit.)
[Boiling point ]

450.8±37.0 °C(Predicted)
[density ]

1.331±0.06 g/cm3(Predicted)
[storage temp. ]

2-8°C
[solubility ]

ethanol: soluble
[form ]

Solid
[pka]

9.31±0.40(Predicted)
[color ]

Pale Yellow to Pale Green
[Sensitive ]

Moisture Sensitive
[BRN ]

2868662
[InChI]

1S/C12H15N3O2S/c1-15(2)11-7-3-6-10-9(11)5-4-8-12(10)18(16,17)14-13/h3-8,14H,13H2,1-2H3
[InChIKey]

KPQYDVAFRDWIBW-UHFFFAOYSA-N
[SMILES]

CN(C)c1cccc2c(cccc12)S(=O)(=O)NN
[CAS DataBase Reference]

33008-06-9(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
[WGK Germany ]

3
[F ]

8-10-21
[HS Code ]

32049010
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

Light yellow powder
[Uses]

Dansylhydrazine (DH) is widely used as a fluorometric reagent for carbonyl compounds. Dansylated carbonyl molecules can be separated and identified by analytical techniques.
[Uses]

Dansylhydrazine can exhibit fluorescence, which can be used for the following:
  • monitoring air pollution by detection of the hydrazones formed by acid-catalyzed derivatization of the carbonyl compounds
  • detection of the separated glycoproteins via sodium dodecyl sulfate polyacrylamide gel electrophoresis(SDS-PAGE)
[General Description]

Dansylhydrazine (DNSH) is a fluorescent reagent which is commonly utilized for derivatization of carbonyl compounds.
[Synthesis]

Using 4'-aminoazobenzene-4-sulfonic acid as raw material, N,N-dimethylaminoazobenzene-4-sulfonic acid was made by methylation; then 4-dimethylaminophenyl azobenzenesulfonyl chloride was made by chlorination with phosphorus pentachloride; 4-dimethylaminoph
Spectrum DetailBack Directory
[Spectrum Detail]

DANSYL HYDRAZINE(33008-06-9)1HNMR
DANSYL HYDRAZINE(33008-06-9)13CNMR
DANSYL HYDRAZINE(33008-06-9)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Dansyl hydrazide, 97%(33008-06-9)
[Sigma Aldrich]

33008-06-9(sigmaaldrich)
[TCI AMERICA]

Dansyl Hydrazine  [for HPLC Labeling],>95.0%(LC)(T)(33008-06-9)
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