ChemicalBook--->CAS DataBase List--->345-92-6

345-92-6

345-92-6 Structure

345-92-6 Structure
IdentificationMore
[Name]

Bis(4-fluorophenyl)-methanone
[CAS]

345-92-6
[Synonyms]

4,4'-DIFLUOROBENZOPHENONE
4,4-DIFLUOROBENZOPHENONE
BDF
BIS(4-FLUOROPHENYL) KETONE
BIS-(4-FLUORO-PHENYL)-METHANONE
DI(4-FLUOROPHENYL)METHANONE
LABOTEST-BB LT00159767
4,4’-difluoro-benzophenon
Benzophenone, 4,4'-difluoro-
bis(4-fluorophenyl)-methanon
Bis(p-fluorophenyl) ketone
bis(p-fluorophenyl)ketone
Di-p-fluorophenyl ketone
di-p-fluorophenylketone
Methanone, bis(4-fluorophenyl)-
p,p’-difluorobenzophenone
p,p'-Difluorobenzophenone
4,4'-Dddifluorobenzophenone
4,4'-Difluorobnzophenone
4,4'-Difluorobenzophenone/Bis(4-Fluorophenyl)Methanone
[EINECS(EC#)]

206-466-3
[Molecular Formula]

C13H8F2O
[MDL Number]

MFCD00000353
[Molecular Weight]

218.2
[MOL File]

345-92-6.mol
Chemical PropertiesBack Directory
[Appearance]

white to slightly yellow crystalline powder
[Melting point ]

102-105 °C (lit.)
[Boiling point ]

137°C (3 torr)
[density ]

1.2543 (estimate)
[vapor pressure ]

0.005Pa at 20℃
[Fp ]

170-172°C/10mm
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

Insoluble in water
[form ]

Crystalline Powder
[color ]

White to slightly yellow
[Water Solubility ]

8.757mg/L at 20℃
[BRN ]

516231
[InChI]

1S/C13H8F2O/c14-11-5-1-9(2-6-11)13(16)10-3-7-12(15)8-4-10/h1-8H
[InChIKey]

LSQARZALBDFYQZ-UHFFFAOYSA-N
[SMILES]

Fc1ccc(cc1)C(=O)c2ccc(F)cc2
[LogP]

3.37 at 20℃
[CAS DataBase Reference]

345-92-6(CAS DataBase Reference)
[NIST Chemistry Reference]

4,4'-Difluorobenzophenone(345-92-6)
[EPA Substance Registry System]

4,4'-Difluorobenzophenone (345-92-6)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335-H411
[Precautionary statements ]

P273-P301+P312+P330-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 3077 9 / PGIII
[WGK Germany ]

3
[RTECS ]

DJ0685000
[Hazard Note ]

Irritant
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

IRRITANT
[HS Code ]

29147000
[Storage Class]

13 - Non Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Aquatic Chronic 2
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Fluorobenzene-->(2-Naphtyl)tributylstannane-->4-FLUORO-(TRI-N-BUTYLSTANNYL)BENZENE-->4,4'-Difluorodiphenylmethane-->4,4'-Difluorobenzhydrol-->4,4'-Dichlorobenzophenone-->4-Fluorobenzoyl chloride-->Dimethyl sulfone-->4-FLUOROBENZENEDIAZONIUM TETRAFLUOROBORATE-->4-Fluorobenzaldehyde
[Preparation Products]

(4-(4-[BIS(4-FLUOROPHENYL)METHYL]PIPERAZIN-1-YL)PHENYL)METHANOL-->1,1'-(4-CHLOROBUTYLIDENE)BIS(4-FLUOROBENZENE)-->4-FLUORO-4'-NITROBENZOPHENONE-->BIS-(4-FLUORO-PHENYL)-PHENYL-METHANOL-->1,1-BIS(4-FLUOROPHENYL)-1-BUTENE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Bis(4-fluorophenyl)-methanone(345-92-6).msds
Hazard InformationBack Directory
[Chemical Properties]

white to slightly yellow crystalline powder
[Uses]

4,4′-Difluorobenzophenone has been used in the study of thermal stability, water uptake and proton conductivity of carboxylated, carboxylated/sulfonated, and crosslinked membranes.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 90, p. 540, 1968 DOI: 10.1021/ja01004a087
[General Description]

4,4′-Difluorobenzophenone is typically used as a starting material for the preparation of polyetheretherketone (PEEK) polymer, a high-temperature thermoplastic, which finds wide use in dentistry as well as in automotive, oil industries, etc.
[Synthesis]

①Mix 200g of fluorobenzene with 65g of anhydrous aluminum trichloride, cool to 0-5℃, add 100g of p-fluorotrichloromethylbenzene dropwise reaction for 20min, get 4,4'-difluorophenyl dichloromethane;

②Add 4,4'-difluorophenyl dichloromethane to 600g

Spectrum DetailBack Directory
[Spectrum Detail]

Bis(4-fluorophenyl)-methanone(345-92-6)MS
Bis(4-fluorophenyl)-methanone(345-92-6)1HNMR
Bis(4-fluorophenyl)-methanone(345-92-6)13CNMR
Bis(4-fluorophenyl)-methanone(345-92-6)IR1
Bis(4-fluorophenyl)-methanone(345-92-6)IR2
Bis(4-fluorophenyl)-methanone(345-92-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4,4'-Difluorobenzophenone, 99%(345-92-6)
[Alfa Aesar]

4,4'-Difluorobenzophenone, 98+%(345-92-6)
[Sigma Aldrich]

345-92-6(sigmaaldrich)
[TCI AMERICA]

4,4'-Difluorobenzophenone,>99.0%(GC)(345-92-6)
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