| Identification | More | [Name]
Cyclopentadienylzirconium trichloride | [CAS]
34767-44-7 | [Synonyms]
CYCLOPENTADIENYLZIRCONIUM(IV) TRICHLORIDE
CYCLOPENTADIENYLZIRCONIUM TRICHLORIDE
TRICHLORO(CYCLOPENTADIENYL)ZIRCONIUM(IV)
CYCLOPENTADIENYLZIRCONIUM TRICHLORIDE, 9
Cyclopentadienylzirkoniumtrichlorid
Cyclopentadienyl Zirconium Trichloride (CpZrCl3)
Cyclopentadienylzirconiumtrichloride,min.98%
Cyclopentadienylzirconium trichloride, 98+%
Cyclopentadienylzirconium trichloride, min. 98% | [Molecular Formula]
C5H5Cl3Zr | [MDL Number]
MFCD00015756 | [Molecular Weight]
262.68 | [MOL File]
34767-44-7.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light brown powder | [Melting point ]
210 °C (dec.)(lit.) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [color ]
off-white to tan | [Water Solubility ]
reacts | [Sensitive ]
Moisture Sensitive | [InChI]
1S/C5H5.3ClH.Zr/c1-2-4-5-3-1;;;;/h1-5H;3*1H;/q;;;;+3/p-3 | [InChIKey]
SULDCQJIUCVYOB-UHFFFAOYSA-K | [SMILES]
Cl[Zr](Cl)Cl.[CH]1[CH][CH][CH][CH]1 | [CAS DataBase Reference]
34767-44-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns.
R29:Contact with water liberates toxic gas.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29319090 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
white to light brown powder | [Uses]
Catalyst for:
- Homo- and copolymerization reactions
- Catalytic dehydrogenation of cyclooctane
- Cross-coupling reaction of aryl fluorides with a phenethyl Grignard reagents
| [reaction suitability]
core: zirconium
reagent type: catalyst | [Synthesis]
Trichloro(cyclopentadienyl)zirconium is prepared by the photoinduced chlorination of Dichlorobis(cyclopentadienyl)zirconium.
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