ChemicalBook--->CAS DataBase List--->350-46-9

350-46-9

350-46-9 Structure

350-46-9 Structure
IdentificationMore
[Name]

4-Fluoronitrobenzene
[CAS]

350-46-9
[Synonyms]

1-FLUORO-4-NITROBENZENE
4-NITROFLUOROBENZENE
P-FLUORONITROBENZENE
P-NITROFLUOROBENZENE
1,4-Fluoronitrobenzene
1-fluoro-4-nitro-benzen
1-Nitro-4-fluorobenzene
4-Fluornitrobenzol
4-fluoro-1-nitrobenzene
Benzene,1-fluoro-4-nitro-
Fluoronitrobenzene3
Fluoronitrobenzenecolorlesssolid
4-Fluoronitrobenzene p-Fluoronitrobenzene
1-Fluoro-4-Nitrobenzene(4-Fluoronitrobenzene
p-Fluoronitrobenzene,99%
4-Fluoronitrobenzene 99%
4-Fluoronitrobenzene99%
1-Fluor-4-nitrobenzol
4-Nitrophenyl fluoride
p-fluoronitorobenzene
[EINECS(EC#)]

206-502-8
[Molecular Formula]

C6H4FNO2
[MDL Number]

MFCD00007282
[Molecular Weight]

141.1
[MOL File]

350-46-9.mol
Chemical PropertiesBack Directory
[Appearance]

yellow liquid
[Melting point ]

21 °C (lit.)
[mp ]

21 °C(lit.)
[Boiling point ]

205 °C (lit.)
[bp ]

205 °C(lit.)
[density ]

1.33 g/mL at 25 °C(lit.)
[vapor density ]

>1 (vs air)
[vapor pressure ]

5.5 mm Hg ( 70 °C)
[refractive index ]

n20/D 1.531(lit.)
[Fp ]

182 °F
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

Liquid After Melting
[color ]

deep greenish-yellow
[Specific Gravity]

1.330
[Stability:]

Stable. Combustible. Incompatible with strong oxidizing agents.
[Water Solubility ]

Insoluble in water.
[Detection Methods]

GC,NMR
[BRN ]

606923
[InChIKey]

WFQDTOYDVUWQMS-UHFFFAOYSA-N
[CAS DataBase Reference]

350-46-9(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzene, 1-fluoro-4-nitro-(350-46-9)
[EPA Substance Registry System]

350-46-9(EPA Substance)
Questions And AnswerBack Directory
[Uses]

4-Nitrofluorobenzene, is an aryl fluorinated building block, and a common intermediate used for the synthesis of many industrial useful compounds. It is used for the preparation of novel soluble aromatic polyimides, such as 1,3,5-Tris(4-aminophenoxy)benzene (TAB).
Safety DataBack Directory
[Hazard Codes ]

Xn,T,Xi
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R33:Danger of cumulative effects.
[Safety Statements ]

S36:Wear suitable protective clothing .
S36/37:Wear suitable protective clothing and gloves .
[RIDADR ]

UN 2811 6.1/PG 3
[WGK Germany ]

1
[RTECS ]

DA1400000
[Hazard Note ]

Toxic/Irritant
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29049085
[Hazardous Substances Data]

350-46-9(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

4-Chloronitrobenzene-->Fluorobenzene-->1-(Trimethylsilyl)-4-nitrobenzene-->4-NITROPHENYL TRIFLUOROMETHANESULFONATE-->4-Nitroaniline
[Preparation Products]

4-Fluoroaniline-->4-(4-AMINOPHENYL)MORPHOLIN-3-ONE-->4-Morpholinoaniline-->4-(1H-PYRAZOL-1-YL)PHENYL ISOTHIOCYANATE-->Pioglitazone-->3-Chloro-4-fluoronitrobenzene-->1-Fluoro-3-nitrobenzene-->N,N-Diethyl-1,4-phenylenediamine-->N,N-DIETHYL-4-NITROANILINE-->4-Phenoxyaniline-->4-Fluoro-N,N-diphenylbenzenamine-->2-Bromo-3-[4-(2-(5-ethyl-2-pyridyl)ethoxy)phenyl]propionic acid methyl ester-->4-Fluoro-3-nitrobenzoic acid-->N,N,N',N'-Tetrakis(4-nitrophenyl)-p-phenylenediamine-->4-(4-FLUOROPHENOXY)ANILINE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

p-Fluoronitrobenzene(350-46-9).msds
Hazard InformationBack Directory
[Chemical Properties]

yellow liquid
[Synthesis Reference(s)]

Journal of the American Chemical Society, 78, p. 6034, 1956 DOI: 10.1021/ja01604a022
Tetrahedron, 52, p. 23, 1996 DOI: 10.1016/0040-4020(95)00867-8
Tetrahedron Letters, 30, p. 7199, 1989 DOI: 10.1016/S0040-4039(01)93933-4
[Purification Methods]

Crystallise it from EtOH. [Beilstein 5 H 241, 5 IV 719.]
Spectrum DetailBack Directory
[Spectrum Detail]

4-Fluoronitrobenzene(350-46-9)MS
4-Fluoronitrobenzene(350-46-9)1HNMR
4-Fluoronitrobenzene(350-46-9)13CNMR
4-Fluoronitrobenzene(350-46-9)IR1
4-Fluoronitrobenzene(350-46-9)Raman
4-Fluoronitrobenzene(350-46-9)ESR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1-Fluoro-4-nitrobenzene, 99%(350-46-9)
[Alfa Aesar]

1-Fluoro-4-nitrobenzene, 99%(350-46-9)
[Sigma Aldrich]

350-46-9(sigmaaldrich)
[TCI AMERICA]

4-Fluoronitrobenzene,>98.0%(GC)(350-46-9)
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