| Identification | More | [Name]
4-Nitrobenzaldehyde | [CAS]
555-16-8 | [Synonyms]
4-FORMYLNITROBENZENE
4-NITROBENZALDEHYDE
AKOS BBS-00003206
p-Formylnitrobenzene
P-NITROBENZALDEHYDE
4-nitro-benzaldehyd
Benzaldehyde, p-nitro-
Benzaldehyde,4-nitro-
Benzaldehyde,p-nitro-
p-nitro-benzaldehyd
p-Nitrobenzaldehyde 4-Nitrobenzaldehyde
4-NITRO BENZALDEHYDE GR
4-Nitrobenzaldehyde,99%
NITROBENZALDEHYDE 4-
4-NITROBENZALDEHYDE/P-NITROBENZALDEHYDE
4-Nitrobenzenecarbaldehyde | [EINECS(EC#)]
209-084-5 | [Molecular Formula]
C7H5NO3 | [MDL Number]
MFCD00007346 | [Molecular Weight]
151.12 | [MOL File]
555-16-8.mol |
| Chemical Properties | Back Directory | [Appearance]
YELLOW TO BROWN CRYSTALLINE POWDER | [Melting point ]
103-106 °C(lit.)
| [Boiling point ]
273.1°C (rough estimate) | [bulk density]
400kg/m3 | [density ]
1,496 g/cm3 | [refractive index ]
1.5800 (estimate) | [storage temp. ]
Store below +30°C. | [solubility ]
2.34g/l | [form ]
Crystalline Powder | [color ]
Yellow to brown | [Odor]
Odorless | [Water Solubility ]
Soluble in water, ethanol, benzene, glacial acetic acid. Slightly soluble in ether. | [Sensitive ]
Air Sensitive | [Detection Methods]
GC,NMR | [Merck ]
14,6587 | [BRN ]
386796 | [InChI]
1S/C7H5NO3/c9-5-6-1-3-7(4-2-6)8(10)11/h1-5H | [InChIKey]
BXRFQSNOROATLV-UHFFFAOYSA-N | [SMILES]
[O-][N+](=O)c1ccc(C=O)cc1 | [CAS DataBase Reference]
555-16-8(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzaldehyde, 4-nitro-(555-16-8) | [EPA Substance Registry System]
555-16-8(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H317-H319 | [Precautionary statements ]
P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36:Irritating to the eyes.
R43:May cause sensitization by skin contact.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36/37/38:Irritating to eyes, respiratory system and skin .
R68:Possible risk of irreversible effects. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S24/25:Avoid contact with skin and eyes .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing . | [WGK Germany ]
2
| [RTECS ]
CU7350000
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [REACH Registrations]
Active | [HS Code ]
29130000 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Sens. 1 | [Toxicity]
LD50 orally in Rabbit: 4700 mg/kg LD50 dermal Rat 16000 mg/kg |
| Hazard Information | Back Directory | [Chemical Properties]
YELLOW TO BROWN CRYSTALLINE POWDER | [Uses]
4-Nitrobenzaldehyde is a benzaldehyde with a nitro group in the para position. It is used as a reagent in decarboxylative aldol reactions that are catalyzed by lipases and proteases in organic co-solvent mixtures. | [Definition]
ChEBI: A C-nitro compound that is benzaldehyde substituted at the para-position with a nitro group. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 78, p. 252, 1956 DOI: 10.1021/ja01582a072
Tetrahedron Letters, 28, p. 4285, 1987 DOI: 10.1016/S0040-4039(00)96486-4 | [Purification Methods]
Purify it as for m-nitrobenzaldehyde above. [Beilstein 7 IV 589.] |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|