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35294-28-1

35294-28-1 Structure

35294-28-1 Structure
IdentificationMore
[Name]

(R)-(+)-2,2'-Dimethoxy-1,1'-binaphthalene
[CAS]

35294-28-1
[Synonyms]

(+/-)-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER
1,1'-BI-2-NAPHTHOL DIMETHYL ETHER
1,1'-BINAPHTHOL DIMETHYL ETHER
2,2'-DIMETHOXY-1,1'-BINAPHTHALENE
(+/-)-2,2'-DIMETHOXY-1,1'-BINAPHTHYL
2,2'-DIMETHOXY-1,1'-BINAPHTHYL
(R)-(+)-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER
(R)-(+)-2,2'-DIMETHOXY-1,1'-BI-NAPHTHOL
(R)-(+)-2,2'-DIMETHOXY-1,1'-BINAPHTHYL
(R)-2,2'-DIMETHOXY-1,1'-BINAPHTHYL
(S)-(-)-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER
(S)-1,1'-BI-2-NAPHTHOL DIMETHYL ETHER
(S)-(-)-2,2'-DIMETHOXY-1,1'-BINAPHTHYL
(S)-(+)-2,2'-DIMETHOXY-1,1'-BINAPHTHYL
(S)-2,2'-DIMETHOXY-1,1'-BINAPHTHYL
(R)-(+)-2,2'-Dimethoxy-1,1'-binaphthalene
(R)-(+)-2,2μ-Dimethoxy-1,1μ-binaphthyl, (R)-1,1μ-Bi-2-naphthyl dimethyl ether
1,1'-Bi(2-methoxynaphthalene)
1,1'-Bi[2-methoxynaphthalene]
[EINECS(EC#)]

233-305-4
[Molecular Formula]

C22H18O2
[MDL Number]

MFCD00091146
[Molecular Weight]

314.38
[MOL File]

35294-28-1.mol
Questions And AnswerBack Directory
[Synthesis]

Using 1-bromo-2-methoxynaphthalene and 2-methoxynaphthalene-1-boronic acid as starting materials, the target compound (R)-(+)-2,2'-Dimethoxy-1,1'-binaphthalene was prepared. The synthetic reaction formula is shown in the figure below:

Synthesis of 35294-28-1

[Uses]

(R)-(+)-2,2'-dimethoxy-1,1'-binaphthyl is a chiral compound and can be used as a chiral reagent.
Chemical PropertiesBack Directory
[Appearance]

white to off-white crystalline powder
[Melting point ]

227-231 °C(lit.)
[Boiling point ]

414.1±30.0 °C(Predicted)
[density ]

1.160±0.06 g/cm3(Predicted)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

powder to crystal
[color ]

White to Almost white
[Optical Rotation]

[α]20/D +52°, c = 1% in chloroform
[BRN ]

4704231
[InChIKey]

BJAADAKPADTRCH-UHFFFAOYSA-N
[CAS DataBase Reference]

35294-28-1(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi,N
[Risk Statements ]

R41:Risk of serious damage to eyes.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R37/38:Irritating to respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/39:Wear suitable protective clothing and eye/face protection .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

3
[HS Code ]

2909.30.6000
Hazard InformationBack Directory
[Chemical Properties]

white to off-white crystalline powder
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

35294-28-1(sigmaaldrich)
[TCI AMERICA]

(R)-2,2'-Dimethoxy-1,1'-binaphthyl(35294-28-1)
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