ChemicalBook--->CAS DataBase List--->36982-84-0

36982-84-0

36982-84-0 Structure

36982-84-0 Structure
IdentificationMore
[Name]

2,4,6-Triisopropylbenzene-sulfonyl azide
[CAS]

36982-84-0
[Synonyms]

2,4,6-TRIISOPROPYLBENZENESULFONYL AZIDE
2,4,6-Triisopropylbenzenesulphonylazide
Trisyl azide
2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water
2,4,6-Triisopropylbenzenesulfonyl azide ,90% [stab. With ca 10% water]
2,4,6-Triisopropylbenzenesulfonic acid azide
[Molecular Formula]

C15H23N3O2S
[MDL Number]

MFCD00859286
[Molecular Weight]

309.43
[MOL File]

36982-84-0.mol
Chemical PropertiesBack Directory
[Melting point ]

39-44 °C
[refractive index ]

n20/D1.499
[Fp ]

4℃
[storage temp. ]

2-8°C
[Water Solubility ]

Insoluble in water.
[Detection Methods]

HPLC,NMR
[BRN ]

2391566
[InChIKey]

AEMWUHCKKDPRSK-UHFFFAOYSA-N
[CAS DataBase Reference]

36982-84-0(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

T,Xn,F
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S15:Keep away from heat .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN1294 - class 3 - PG 2 - Toluene, solution
[WGK Germany ]

3
[HS Code ]

29350090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium azide-->2,4,6-Triisopropylbenzenesulfonyl chloride
Hazard InformationBack Directory
[Chemical Properties]

White wet solid
[Uses]

2,4,6-Triisopropylbenzenesulfonyl azide is used as a reagent for diazo transfer to ketones, e.g. under phase-transfer conditions, giving better yields of sterically-hindered ?-diazo ketones than other methods. It is also used for azide transfer to potassium enolates (KHMDS) to form the ?-azido derivatives.
[Uses]

Reagent for:• ;Stereoselective diversity-oriented synthesis of functionalized saccharides1• ;Meyer′s lactamization2Reagent for synthesis of:• ;Antidote to anthrax lethal factor intoxication3• ;Bacterial RNA polymerase inhibitor4• ;Bicyclic extended dipeptide surrogates5• ;Single enantiomers of mycobacterial keomycolic acids6
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

2,4,6-Triisopropylbenzenesulfonyl azide, 98%, stab. with ca 10% water(36982-84-0)
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