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37526-88-8

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37526-88-8 Structure

37526-88-8 Structure
IdentificationMore
[Name]

BENZYL TIGLATE
[CAS]

37526-88-8
[Synonyms]

BENZYL 2-METHYL-2-BUTENOATE
BENZYL TIGLATE
BENZYL TRANS-2-METHYL-2-BUTENOATE
FEMA 3330
TIGLIC ACID BENZYL ESTER
2-Butenoic acid, 2-methyl-, phenylmethyl ester, (E)-
2-Butenoicacid,2-methyl-,phenylmethylester,(E)-
2-methyl-,phenylmethylester,(e)-2-butenoicaci
2-methyl-,phenylmethylester,(E)-2-Butenoicacid
Benzyl (2E)-2-methyl-2-butenoate
trans-2-Butenoic acid, 2-methyl-, phenylmethyl ester
trans-2-Butenoicacid,2-methyl-,phenylmethylester
Benzyl trans-2,3-dimethylacrylate~Benzyl (E)-2-methyl-2-butenoate~Tiglic acid benzyl ester
benzyl 2-methylcrotonate
BENZYL TRANS-2-METHYL-2-BUTENOATE 90+%
2-Butenoic acid, 2-methyl-, phenylmethyl ester, (2E)-
benzyl (e)-2-methyl-2-butenoate
benzyl trans-2,3-dimethylacrylate
Benzyl-2-methylcrotonat
(E)-2-Methyl-2-butenoic acid benzyl ester
[EINECS(EC#)]

253-544-8
[Molecular Formula]

C12H14O2
[MDL Number]

MFCD00017279
[Molecular Weight]

190.24
[MOL File]

37526-88-8.mol
Chemical PropertiesBack Directory
[Boiling point ]

139 °C9 mm Hg(lit.)
[density ]

1.031 g/mL at 25 °C(lit.)
[FEMA ]

3330
[refractive index ]

n20/D 1.522(lit.)
[Fp ]

>230 °F
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Odor]

at 100.00 %. balsamic earthy mushroom vegetable plastic cortex almond nutty
[Odor Type]

balsamic
[JECFA Number]

846
[BRN ]

2556119
[LogP]

3.35
[CAS DataBase Reference]

37526-88-8(CAS DataBase Reference)
[EPA Substance Registry System]

2-Butenoic acid, 2-methyl-, phenylmethyl ester, (2E)- (37526-88-8)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

2
[TSCA ]

Yes
[HS Code ]

29161900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Benzyl alcohol-->Tiglic acid-->Butanoic acid, 2-hydroxy-2-methyl-, phenylmethyl ester, (2S)--->Monobenzone-->(S)-(+)-2-Methylbutyric acid-->Phenol-->o-Cresol-->2,6-Dimethoxyphenol-->Guaiacol-->4-Nitrophenol
Hazard InformationBack Directory
[Chemical Properties]

Benzyl tiglate has an odor reminiscent of mushroom, with a rosy undertone.
[Occurrence]

Reported found in clove bud and rose apple (Syz. jambos Alston).
[Uses]

Tiglic Acid Benzyl Ester is found as one of the Geranium essential oils, and essential oil and solvent extracts of Iris planifolia (Mill) from Algeria, possessing antibacterial activity. It is also the starting material in the synthesis of (S)-α-Acetolactic Acid (A163805).
[Definition]

ChEBI: Benzyl trans-2-methyl-2-butenoate is a carboxylic ester. It is functionally related to a benzyl alcohol.
[Preparation]

By direct esterification of tiglic acid with benzyl alcohol under azeotropic conditions.
[Taste threshold values]

Taste characteristics at 100 ppm: sweet, balsamic, spice-like with a nutty almond note.
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Benzyl tiglate, 97%(37526-88-8)
[TCI AMERICA]

Benzyl Tiglate,>97.0%(GC)(37526-88-8)
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