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37677-14-8

37677-14-8 Structure

37677-14-8 Structure
IdentificationBack Directory
[Name]

MYRAC ALDEHYDE
[CAS]

37677-14-8
[Synonyms]

Myrac
EMPETAL
empetaal
MYRALDENE
para-myracaldehyde
MYRAC ALDEHYDE USP/EP/BP
MYRAC AMYRAC ALDEHYDELDEHYDE
ISOHEXENYL TETRAHYDRO BENZALDEHYDE
1-Formyl-4-isohexenyl-4-cyclohexene
1-Formyl-4-ixohexenyl-4-cyclohexene
Isohexenylcyclohexenylcarboxaldehyde
4-(4-Methyl-3-pentenyl)-1-formyl-3-cyclohexene
1-(4-methyl-3-pentenyl)-4-formyl-1-cyclohexene
1-(4-Methyl-3-pentenyl)cyclohexene-4-carbaldehyde
4-(4-Methyl-3-pentenyl)cyclohex-3-en-1-carbaldehyd
4-(4-methylpent-3-enyl)cyclohex-3-ene-1-carbaldehyde
4-(4-Methylpent-3-en-1-yl)cyclohex-3-enecarbaldehyde
4-(4-methyl-3-pentenyl)cyclohex-3-ene-1-carbaldehyde
3-cyclohexene-1-carboxaldehyde,-(4-methyl-pentenyl)-
4-(4-Methyl-3-pentenyl)-3-cyclohexene-1-carbaldehyde
4-(4-methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyd
4-(4-methyl-3-pentenyl)-3-Cyclohexene-1-carboxaldehyde
4-(4-Methylpent-3-enyl)cyclohex-3-ene-1-carboxaldehyde
3-cyclohexene-1-carboxaldehyde,-(4-methyl-3-pentenyl)-
4-(4-Methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde
4-(4-Methyl-3-penten-1-yl)-3-cyclohexen-1-carboxaldehyde
3-Cyclohexene-1-carboxaldehyde, 4-(4-methyl-3-pentenyl)-
4-(4-METHYL-3-PENTENYL)-3-CYCLOHEXENE-1-CARBOXALDEHYDE,98%
4-(4-Methyl-3-penten-1-yl)-3-cyclohexene-1-carboxyaldehyde
[EINECS(EC#)]

253-617-4
[Molecular Formula]

C13H20O
[MDL Number]

MFCD00169827
[MOL File]

37677-14-8.mol
[Molecular Weight]

192.3
Chemical PropertiesBack Directory
[Boiling point ]

108 °C(Press: 1.6 Torr)
[density ]

0.933 g/cm3
[Fp ]

>93.3°
[storage temp. ]

2-8°C, stored under nitrogen
[color ]

Colourless oily liquid
[Odor]

at 10.00 % in dipropylene glycol. citrus greasy aldehydic floral marine
[Odor Type]

aldehydic
[Cosmetics Ingredients Functions]

PERFUMING
[LogP]

4.700
[NIST Chemistry Reference]

3-Cyclohexene-1-carboxaldehyde, 4-(4-methyl-3-pentenyl)-(37677-14-8)
[EPA Substance Registry System]

3-Cyclohexene-1- carboxaldehyde, 4-(4-methyl-3-pentenyl)-(37677-14-8)
Questions And AnswerBack Directory
[Uses]

MYRAC ALDEHYDE can be used in citrus, fruity, and many floral fragrances. It has a significant impact on bergamot and other citrus scents, including aldehyde top notes. Because it is more stable than most aliphatic aldehydes, it has a wider range of applications. It is excellent for scenting soaps and can enhance the freshness of everyday fragrances such as pine needle, lily of the valley, violet, and lilac. It can also be used as a masking agent for unpleasant industrial odors. It blends well with ionone and cyclohexyl derivatives of cypress wood. The dosage in fragrances can reach 5%–10%. It is generally not used for food.
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Health Hazard (GHS08)Environment (GHS09)
GHS07,GHS08,GHS09
[Signal word ]

Danger
[Hazard statements ]

H317-H411-H372
[Precautionary statements ]

P261-P272-P273-P280-P302+P352-P321-P333+P313-P363-P391-P501
[RIDADR ]

UN3082
[TSCA ]

TSCA listed
[HazardClass ]

9
[Toxicity]

Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg
Hazard InformationBack Directory
[Hazard]

Low toxicity by ingestion. A moderate skin and mild eye irritant.
[Chemical Properties]

MYRAC ALDEHYDE is prepared, together with its 3-isomer, by a Diels–Alder reaction ofmyrcene and acrolein.Themixture, d20 4 0.927–0.935, n20 D 1.488–1.492, has a fresh, fruity, slightly citrus-like odor and is used to perfume household products.
[Occurrence]

Has apparently not been reported to occur in nature
[Definition]

ChEBI: 4-(4-Methyl-3-pentenyl)-3-cyclohexene-1-carboxaldehyde is a monoterpenoid.
[Preparation]

From myrcene and acrolein (Arctander, 1969).
[Trade name]

Myrac aldehyde (IFF), Myraldene (Givaudan), Myracal (DRT).
Spectrum DetailBack Directory
[Spectrum Detail]

MYRAC ALDEHYDE(37677-14-8)1HNMR
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