ChemicalBook--->CAS DataBase List--->38053-91-7

38053-91-7

38053-91-7 Structure

38053-91-7 Structure
IdentificationMore
[Name]

2-(Trimethylsiloxy)-1,3-butadiene
[CAS]

38053-91-7
[Synonyms]

2-(TRIMETHYLSILOXY)-1,3-BUTADIENE
2-TRIMETHYLSILYLOXY-1,3-BUTADIENE
Trimethylsiloxybutadiene
Silane, trimethyl(1-methylene-2-propenyl)oxy-
2-(TRIMETHYLSILOXY)-1,3-BUTADIENE 98+%
(1-Methyleneallyloxy)trimethylsilane
1,3-Butadiene-2-yloxytrimethylsilane
Trimethyl[(1-methylene-2-propenyl)oxy]silane
[Molecular Formula]

C7H14OSi
[MDL Number]

MFCD00009852
[Molecular Weight]

142.27
[MOL File]

38053-91-7.mol
Chemical PropertiesBack Directory
[Melting point ]

<0°C
[Boiling point ]

50 °C
[density ]

0.807
[refractive index ]

1.4480
[Fp ]

12°C
[storage temp. ]

Refrigerator
[solubility ]

sol most standard organic solvents.
[form ]

clear liquid
[color ]

Colorless to Light yellow to Light orange
[Specific Gravity]

0.807
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[InChI]

1S/C7H14OSi/c1-6-7(2)8-9(3,4)5/h6H,1-2H2,3-5H3
[InChIKey]

JOAPBVRQZQYKMS-UHFFFAOYSA-N
[SMILES]

[Si](OC(=C)C=C)(C)(C)C
[CAS DataBase Reference]

38053-91-7(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)
GHS02
[Signal word ]

Danger
[Hazard statements ]

H225
[Precautionary statements ]

P210-P233-P240-P241-P242-P243
[Risk Statements ]

R11:Highly Flammable.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

1992
[WGK Germany ]

WGK 3 highly water endangering
[Autoignition Temperature]

350 °C
[TSCA ]

No
[HS Code ]

2931 90 00
[HazardClass ]

3
[PackingGroup ]

II
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Flam. Liq. 2
Hazard InformationBack Directory
[Physical properties]

bp 50–55 °C/50 mmHg; d 0.811 g cm?3.
[Uses]

2-Trimethylsilyloxy-1,3-butadiene is easily prepared reactive diene for Diels–Alder reactions and other cycloadditions; reactive silyl enol ether for aldol,Michael reactions, and electrophilic additions. It participates in the reactions of Diels–Alder Reactions, Heterodienophiles, [2 + 2] and Other Cycloadditions, Carbene Additions, Aldol Condensations and Electrophilic Additions.
[Preparation]

2-Trimethylsilyloxy-1,3-butadiene can be prepared easily from methyl vinyl ketone.
[Precautions]

2-(Trimethylsiloxy)-1,3-butadiene is a flammable liquid and is moisture sensitive.
Spectrum DetailBack Directory
[Spectrum Detail]

2-(Trimethylsiloxy)-1,3-butadiene(38053-91-7)1HNMR
2-(Trimethylsiloxy)-1,3-butadiene(38053-91-7)13CNMR
2-(Trimethylsiloxy)-1,3-butadiene(38053-91-7)IR1
Well-known Reagent Company Product InformationBack Directory
[TCI AMERICA]

2-Trimethylsilyloxy-1,3-butadiene,>95.0%(GC)(38053-91-7)
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