| Identification | More | [Name]
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE | [CAS]
59414-23-2 | [Synonyms]
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
1-METHOXY-3-(TRIMETHYLSILOXY)BUTADIENE
1-METHOXY-3-TRIMETHYLSILYLOXY-1,3-BUTADIENE
DANISHEFSKY'S DIENE
TRANS-1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
TRANS-1-METHOXY-3-(TRIMETHYLSILYLOXY)-1,3-BUTADIENE
([(2E)-3-Methoxy-1-methylene-2-propenyl]oxy)(trimethyl)silane
[(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl-silan
Silane, [(3-methoxy-1-methylene-2-propenyl)oxy]trimethyl-
methyl 3-trimethylsilyloxybuta-1,3-dien-1-yl ether
1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene, GC 90%
(3Z)-4-METHOXYBUTA-1,3-DIEN-2-YL]OXY-TRIMETHYL-SILANE
(3-Methoxy-1-methyleneallyloxy)trimethylsilane
3-(Trimethylsilyloxy)-1-methoxy-1,3-butadiene
4-Methoxy-1,3-butadiene-2-yloxytrimethylsilane
4-Methoxy-2-(trimethylsiloxy)-1,3-butadiene
4-Methoxy-2-(trimethylsilyloxy)-1,3-butadiene
Trimethyl[(1-methylene-3-methoxy-2-propenyl)oxy]silane | [EINECS(EC#)]
261-753-0 | [Molecular Formula]
C8H16O2Si | [MDL Number]
MFCD00008498 | [Molecular Weight]
172.3 | [MOL File]
59414-23-2.mol |
| Safety Data | Back Directory | [Risk Statements ]
R10:Flammable. | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes . | [RIDADR ]
UN 1993 3/PG 3
| [WGK Germany ]
3
| [F ]
10-21 | [TSCA ]
TSCA listed | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29310099 |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR LIGHT YELLOW TO BROWN LIQUID | [Uses]
1-Methoxy-3-trimethylsilyloxy-1,3-butadiene is used as a highly reactive diene for Diels-Alder reactions and hetero-Diels-Alder reactions. | [Preparation]
1-Methoxy-3-trimethylsilyloxy-1,3-butadiene was originally prepared from 4-Methoxy-3-buten-2-one with Chlorotrimethylsilane-Triethylamine-Zinc Chloride in benzene as shown below (68% yield, eq 1). At the present time, the most efficient method is to use TMSCl-Lithium Bromide-Et3N in THF (91%).
| [storage]
1-Methoxy-3-trimethylsilyloxy-1,3-butadiene can be kept in a stoppered container without appreciable decomposition, but it is extremely moisture sensitive.
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J & K SCIENTIFIC LTD.
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Energy Chemical
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www.energy-chemical.com |
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T&W GROUP
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