| Identification | More | [Name]
Valienamine | [CAS]
38231-86-6 | [Synonyms]
(1S,2S,3R,6S)-6-Amino-4-(hydroxymethyl)-4-cyclohexene-1,2,3-triol (1S,2S,3R,6S)-6-AMINO-4-(HYDROXYMETHYL)CYCLOHEX-4-ENE-1,2,3-TRIOL (1S,2S,3R,6S)-6AMINO-4-(HYDROXYMETHYL)CYCLOHEX-4-ENE-1,2,3-TRIOL HYDROCHLORIDE 4-AMINO-2-(HYDROXYMETHYL)CYCLOHEX-2-ENE-1,5,6-TRIOL 6-AMINO-4-(HYDROXYMETHYL)-4-CYCLOPEXENE-1,2,3-TRIOL, HYDROCHLORIDE VALIENAMINE (+)-VALIENAMINE, HYDROCHLORIDE VALIENAMINE HCL 6-Amino-4-(hydroxymethyl)-4-cyclopexene-1,2,3-triolHCl (+)-Valienamine (1S,2S,3R,6S)-6-Amino-4-(hydroxymethyl)-4-cyclopexene-1,2,3-triol Hydrochloride (1S)-6α-Amino-4-(hydroxymethyl)-4-cyclohexene-1α,2β,3α-triol 6α-Amino-4-(hydroxymethyl)-4-cyclohexene-1α,2β,3α-triol | [Molecular Formula]
C5H12N2O2 | [MDL Number]
MFCD07357238 | [Molecular Weight]
132.16 | [MOL File]
38231-86-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Slightly Yellow Solid | [Boiling point ]
377.3±42.0 °C(Predicted) | [density ]
1.525±0.06 g/cm3(Predicted) | [storage temp. ]
Hygroscopic, Store under Inert atmosphere Refrigerator | [solubility ]
Water (Slightly) | [form ]
Solid | [pka]
13.47±0.70(Predicted) | [color ]
Slightly Yellow to Dark Brown | [Usage]
A glucosidase inhibitor which does not anomerise and undergo hydrolysis | [Stability:]
Hygroscopic | [CAS DataBase Reference]
38231-86-6(CAS DataBase Reference) |
| Questions And Answer | Back Directory | [Preparation]
Using inositol methyl ether as a raw material, it is converted into a diisopropylidene compound, catalytically oxidized to a ketone, stereoselectively epoxidized, hydrolyzed, the epoxy ring broken, two dimethyl ether bonds broken and disassembled, triisopropylated, selectively hydrolyzed and benzylated trans-isopropylidene, and then hydrolyzed again to the remaining two isopropylidene groups. Following selective benzoylation, methanesulfonation, epoxidation, acetylation, and elimination of the epoxy ring to form cyclohexenone, the acyl group is removed, selectively benzoylated, hydroxyazidated, and the azido group is reduced to an amino group and deprotected to obtain Valienamine. |
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| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
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