| Identification | More | [Name]
(-)-Camphanic acid chloride | [CAS]
39637-74-6 | [Synonyms]
[1S]-3-OXO-4,7,7-TRIMETHYL-2-OXABICYCLO[2.2.1]HEPTANE-1-CARBONYL CHLORIDE
(1S)-3-OXO-4,7,7-TRIMETHYL-2-OXABICYCLO[2.2.1]HEPTANE-1-CARBOXYL CHLORIDE
(-)-(1S,4R)-CAMPHANOYL CHLORIDE
(1S)-(-)-CAMPHANIC CHLORIDE
(1S)-(-)-CAMPHANOYL CHLORIDE
(1S)-(-)CAMPHANYL CHLORIDE
(-)-CAMPHANIC ACID CHLORIDE
(-)-CAMPHANIC CHLORIDE
(S)-(-)-1-CAMPHANYL CHLORIDE
(1S)-(-)-Camphanicacidchloride
(1S)-(−
)-Camphanic chloride
3-oxa-2-oxobornane-4-carbonyl chloride
(1S,4R)-(-)-Camphanic chloride
(1S)-(-)-Camphanic chloride, 98% (99% EE)
(-)-CAMPHANIC ACID CHLORIDE 98%
(1S)-(-)-Camphanicchloride,95%
(+)-(1R,4S)-Camphanoyl chloride
2-Oxabicyclo2.2.1heptane-1-carbonyl chloride, 4,7,7-trimethyl-3-oxo-, (1S,4R)-
(-)-Camphanic acid chloride
(-)-Camphanoyl chloride | [EINECS(EC#)]
254-552-4 | [Molecular Formula]
C10H13ClO3 | [MDL Number]
MFCD00135626 | [Molecular Weight]
216.66 | [MOL File]
39637-74-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Off-White Powder | [Melting point ]
71-73 °C(lit.)
| [alpha ]
-18 º (c=2, CCl4) | [Boiling point ]
310.92°C (rough estimate) | [density ]
1.2072 (rough estimate) | [refractive index ]
1.5390 (estimate) | [storage temp. ]
−20°C
| [solubility ]
soluble in Dichloromethane, Ether, Ethyl Acetate, Methanol | [form ]
Powder | [color ]
Yellow to orange-brown | [Optical Rotation]
[α]23/D 18°, c = 2 in carbon tetrachloride | [Water Solubility ]
decomposes | [Sensitive ]
Moisture Sensitive | [Usage]
An optically active resolving agent | [Detection Methods]
GC | [BRN ]
3590860 | [InChIKey]
PAXWODJTHKJQDZ-RGURZIINSA-N | [CAS DataBase Reference]
39637-74-6(CAS DataBase Reference) | [Storage Precautions]
Moisture sensitive |
| Safety Data | Back Directory | [Hazard Codes ]
C,Xi | [Risk Statements ]
R34:Causes burns.
R29:Contact with water liberates toxic gas. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S8:Keep container dry .
S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29322090 |
| Hazard Information | Back Directory | [Chemical Properties]
Off-White Powder | [Uses]
An optically active resolving agent | [General Description]
(1S)-(-)-Camphanic chloride is a chiral derivatizing agent. It can be prepared by reacting (-)-(1S,4R)-camphanic acid with thionyl chloride. | [Purification Methods]
It is soluble in toluene (50g/100mL at 0o) and crystallises from pet ether (b 40-60o). It sublimes at 70o/5mm, Store it dry at 0o, max (CCl4) 1805s and 1780m cm-1. Armarego et al. J Chem Soc, Perkin Trans I 2229 1976, Gerlach Helv Chim Acta 51 1587 1968, Gerlach Helv Chim Acta 68 1815 1985, Beilstein 18/8 V 101.] |
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