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405204-22-0

405204-22-0 Structure

405204-22-0 Structure
IdentificationBack Directory
[Name]

LanthanuM(III) chloride bis(lithiuM chloride) coMplex solution 0.6 M in THF
[CAS]

405204-22-0
[Synonyms]

oride bis(L
dilithium,trichlorolanthanum,dichloride
Lanthanum(III) chloride bis(lithium chloride) complex
Lanthanum(III) chloride bis(lithium chloride) complex solution
LanthanuM(III) chloride bis(lithiuM chloride) coMplex solution 0.6 M in THF
[Molecular Formula]

Cl5LaLi-
[MDL Number]

MFCD15144757
[MOL File]

405204-22-0.mol
[Molecular Weight]

323.1
Chemical PropertiesBack Directory
[density ]

1.05 g/mL at 25 °C
[Fp ]

17℃
[form ]

liquid
[InChI]

InChI=1S/5ClH.La.Li/h5*1H;;/q;;;;;+3;+1/p-5
[InChIKey]

IDVOGQXAVMAMCY-UHFFFAOYSA-I
[SMILES]

[La+3]([Cl-])([Cl-])([Cl-])([Cl-])[Cl-].[Li+]
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS02,GHS05,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H225-H290-H302-H317-H318-H335-H351-H412
[Precautionary statements ]

P210-P280-P301+P312+P330-P305+P351+P338+P310-P370+P378-P403+P235
[Hazard Codes ]

F,Xn
[Risk Statements ]

11-19-36/37/38-40
[Safety Statements ]

16-26-36/37
[RIDADR ]

UN 2056 3 / PGII
[WGK Germany ]

2
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Aquatic Chronic 3
Carc. 2
Eye Dam. 1
Flam. Liq. 2
Met. Corr. 1
Skin Sens. 1
STOT SE 3
Hazard InformationBack Directory
[Uses]

Selective 1,2-Additions with LaCl3?2LiCl

  • Mediates Grignard additions
  • Reagent for metal exchange reactions
  • Promoter for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines
[reaction suitability]

reagent type: catalyst
core: lanthanum
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