ChemicalBook--->CAS DataBase List--->29046-78-4

29046-78-4

29046-78-4 Structure

29046-78-4 Structure
IdentificationBack Directory
[Name]

NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT
[CAS]

29046-78-4
[Synonyms]

(DME)NiCl2
oride ethyL
NiCl2 glyme
DIMETHOXYETHANE ADDUCT
Dichloro(dimethoxyethane)nickel
NICKEL CHLORIDE, DIMETHOXYETHANE
dichloronickel,1,2-dimethoxyethane
Dichloro(1,2-dimethoxyethane)nickel
NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT
Nickel,dichloro[1,2-di(methoxy-kO)ethane]-
NICKEL(II) CHLORIDE DIMETHOXYETHANE ADDUCT
Nickel, dichloro[1,2-di(methoxy-κO)ethane]-
Nickel(II) Chloride Dimethoxyethane Complex
Nickel(II) chloride ethylene glycol dimethyl
NICKEL(II)CHLORIDE,DIMETHOXYETHANEADDUCT,MIN.97%
Nickel(II) chloride ethylene glycol dimethyl ether
Nickel(II) chloride, dimethoxyethane adduct, min. 97%
NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT ISO 9001:2015 REACH
Nickel(II) chloride ethylene glycol diMethyl ether coMplex 98%
Nickel(II) chloride ethylene glycol dimethyl ether complex
[Molecular Formula]

C4H10Cl2NiO2
[MDL Number]

MFCD00013481
[MOL File]

29046-78-4.mol
[Molecular Weight]

219.72
Chemical PropertiesBack Directory
[Melting point ]

>300 °C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[color ]

yellow
[Relative polarity]

0.231
[Sensitive ]

moisture sensitive
[InChI]

1S/C4H10O2.2ClH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2
[InChIKey]

OCMNCWNTDDVHFK-UHFFFAOYSA-L
[SMILES]

Cl[Ni]Cl.COCCOC
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

23/24/25-36/37/38-42/43-45-50/53-43-36/38-25
[Safety Statements ]

26-36/37/39-61-60-45-36/37-53
[RIDADR ]

3288
[WGK Germany ]

3
[HazardClass ]

6.1
[Storage Class]

4.3 - Hazardous materials which set free flammable gases upon contact with water
[Hazard Classifications]

Acute Tox. 3 Oral
Aquatic Acute 1
Carc. 1B
Eye Irrit. 2
Resp. Sens. 1
Skin Irrit. 2
Water-react 2
Hazard InformationBack Directory
[Uses]

Nickel(II) chloride ethylene glycol dimethyl ether complex can be used:
  • As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters.
  • As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF3 compounds.
  • For the synthesis of nickel bis(benzimidazol-2-ylidene) pincer complexes which can be used for electrocatalytic reduction of CO2 to CO.
  • As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light.

[Uses]

Nickel(II) chloride ethylene glycol dimethyl ether is commonly used as a catalyst for the synthesis of various organic compounds.
[reaction suitability]

core: nickel
reagent type: catalyst
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