| Identification | More | [Name]
1-Iodoheptane | [CAS]
4282-40-0 | [Synonyms]
1-IODOHEPTANE
HEPTYL IODIDE
N-HEPTYL IODIDE
1-iodo-heptan
1-Iodomeptane
Heptane, 1-iodo-
heptane,1-iodo-
Heptyljodid
I-Iodoheptane
1-Iodoheptane99%
1-Iodoheptane,98%
1-Jodheptan
1-Iodoheptane (stabilized with Copper chip) | [EINECS(EC#)]
224-285-8 | [Molecular Formula]
C7H15I | [MDL Number]
MFCD00001104 | [Molecular Weight]
226.1 | [MOL File]
4282-40-0.mol |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless to pale yellow-orange liquid | [Melting point ]
-48 °C (lit.) | [Boiling point ]
204 °C (lit.) | [density ]
1.379 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.490(lit.)
| [Fp ]
174 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
benzene: miscible(lit.) | [form ]
clear liquid | [color ]
Colorless to Brown | [Specific Gravity]
1.379 | [Water Solubility ]
immiscible | [Sensitive ]
Light Sensitive | [BRN ]
1697161 | [Dielectric constant]
4.9（22℃） | [CAS DataBase Reference]
4282-40-0(CAS DataBase Reference) | [NIST Chemistry Reference]
1-Iodoheptane(4282-40-0) | [EPA Substance Registry System]
4282-40-0(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [RTECS ]
MJ1050000 | [F ]
8 | [Hazard Note ]
Irritant | [TSCA ]
Yes | [HS Code ]
29033080 |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to pale yellow-orange liquid | [Uses]
1-Iodoheptane is used in the functionalization of symmetrical star-shaped molecules with carborane clusters. | [Synthesis]
The Synthesis of 1-iodoheptane is as follows:
Firstly, catechol reacts with phosphorus trichloride to produce o-phenylene phosphorous acid chloride, and then the produced compound reacts with heptanol to obtain colorless oily phosphite. Second, take 50.9g (0.20mol) of the above phosphite and 50.8g (0.20mol) of iodine into 500ml of dichloromethane. After that, stir at room temperature for 1h. Finally, use 10% sodium thiosulfate solution to wash away the unreacted iodine that may exist, then wash with 5% NaOH solution, 5% NaHCO3 solution, and saturated NaCl solution in turn, separate the organic phase, evaporate the solvent, and depressurize Distill and collect fractions at 96-104°C (5.33-6.4kPa) to obtain 39g 1-Iodoheptane with a yield of 86%. |
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