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435294-03-4

435294-03-4 Structure

435294-03-4 Structure
IdentificationBack Directory
[Name]

Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III)
[CAS]

435294-03-4
[Synonyms]

(piq)2Ir(acac)
Bis(1-phenyl-isoquinoline)(Acetylacetonato)iridium(III)
IridiuM (III) bis(1-phenylisoquinolyl-N,C2') acetylacetonate
Ir(piq)2(acac) , Bis(1-phenylisoquinoline)(acetylacetonato)ir
Bis[2-(1-isoquinolinyl-N)phenyl-C](2,4-pentanedionato-O2,O4)iridium(III)
iridium(III) 4-oxopent-2-en-2-olate bis(2-(isoquinolin-1-yl)benzen-1-ide)
[Molecular Formula]

C35H27N2O2Ir
[MDL Number]

MFCD12022533
[MOL File]

435294-03-4.mol
[Molecular Weight]

700.826
Chemical PropertiesBack Directory
[Melting point ]

366-370°C
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[form ]

powder or crystals
[color ]

Red
[λmax]

341 nm in dichloromethane
476 nm in dichloromethane
[InChI]

InChI=1S/2C15H10N.C5H8O2.Ir/c2*1-2-7-13(8-3-1)15-14-9-5-4-6-12(14)10-11-16-15;1-4(6)3-5(2)7;/h2*1-7,9-11H;3,6H,1-2H3;/q2*-1;;/b;;4-3-;
[InChIKey]

SQMQOSSYPCILHQ-DVACKJPTSA-N
[SMILES]

CC(=O)[CH-]C(C)=O.[Ir+](c1ccccc1-c2nccc3ccccc23)c4ccccc4-c5nccc6ccccc56
[Absorption]

λmax?302 nm in THF
[Odor]

Red powder/crystals
Hazard InformationBack Directory
[Description]

Bis(1-phenylisoquinoline)(acetylacetonate)iridium(III),?Ir(piq)2(acac) is widely used as an efficient phosphorescent red emitter dopant material in PhOLED devices.?It was reported that the piq ligand can?partially?suppress?the triplet-triplet annihilation and show short phosphorescent lifetime [2].
[Uses]

High efficiency Red Dopant Material for OLED devices. 17 Cd/A current efficiency; 10 lm/W power efficiency; and 8.8% external quantum efficiency can be achieved for devices using this material.
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H317-H335-H411-H227
[Precautionary statements ]

P501-P261-P273-P272-P210-P271-P264-P280-P302+P352-P370+P378-P391-P337+P313-P305+P351+P338-P362+P364-P333+P313-P304+P340+P312-P403+P233-P403+P235-P405
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Classification]

Organometallic complex, Phosphorescent red emitter, Red dopant, OLED and PLED materials, Sublimed materials.
[Applications]

Bis(1-phenylisoquinoline)(acetylacetonate)iridium(III), Ir(piq)2(acac) is widely used as an efficient phosphorescent red emitter dopant material in PhOLED devices. It was reported that the piq ligand can partially suppress the triplet-triplet annihilation and show short phosphorescent lifetime.
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