| Identification | Back Directory | [Name]
TRIPHENYLCARBENIUM HEXAFLUOROPHOSPHATE | [CAS]
437-17-2 | [Synonyms]
NSC 176018
Trityl cationhexaf
TRITYL HEXAFLUORO-PHOSPHATE
TRITYLIUM HEXAFLUOROPHOSPHATE
Trityl cation·hexafluorophosphate
Triphenylmethyl hexafluorophosphate
Triphenylcarbonium hexafluorophosphate
Triphenylmethylium·hexafluorophosphate
TRIPHENYLCARBENIUM HEXAFLUOROPHOSPHATE
triphenyl-methyliuhexafluorophosphate(1-)
Triphenylcarbenium hexafluorophosphate,99%
Trityl hexafluorophosphate, Tritylium hexafluorophosphate | [EINECS(EC#)]
207-112-0 | [Molecular Formula]
C19H15F6P | [MDL Number]
MFCD00013121 | [MOL File]
437-17-2.mol | [Molecular Weight]
388.29 |
| Chemical Properties | Back Directory | [Appearance]
OCHRE TO ORANGE POWDER | [Melting point ]
~150 °C (dec.)(lit.)
| [storage temp. ]
2-8°C
| [form ]
solid | [Water Solubility ]
Soluble in water. (27 g/L) at 25°C. | [Sensitive ]
Moisture Sensitive | [BRN ]
4344297 | [InChI]
1S/C19H15.F6P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7(2,3,4,5)6/h1-15H;/q+1;-1 | [InChIKey]
IBTFOFOFRZKIJU-UHFFFAOYSA-N | [SMILES]
F[P-](F)(F)(F)(F)F.c1ccc(cc1)[C+](c2ccccc2)c3ccccc3 | [EPA Substance Registry System]
Methylium, triphenyl-, hexafluorophosphate(1-) (437-17-2) |
| Hazard Information | Back Directory | [Chemical Properties]
OCHRE TO ORANGE POWDER | [Uses]
Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of "push-pull" tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst. | [storage]
Trityl hexafluorophosphate should be stored in the dark as exposure to light darkens the compound. It is rapidly hydrolyzed by exposure to moist air. |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
34 | [Safety Statements ]
26-36/37/39-45 | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
8-10 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
|
| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|