| Identification | More | [Name]
Hexafluorophosphoric acid | [CAS]
16940-81-1 | [Synonyms]
HEXAFLUOROPHOSPHORIC ACID
HexafluorophoSphoric acid，anhydrous
HYDROGEN HEXAFLUOROPHOSPHATE
fluorophosphoricacid[hpf6]
hexafluoro-phosphate(1-hydrogen
hexafluorophosphoric
hydrogenhexafluorophosphate(1-)
Hexafluorophsophoric acid
HEXAFLUOROPHOSPHORIC ACID,~65% IN WATER (GRAVIMETRIC)
HEXAFLUOROPHOSPHORIC ACID, 60 WT. % SOLU TION IN WATER
HexafluorophosphoricAcidPowder
Hexafluorophosphoricacid,aqueoussolution
HEXAFLUOROPHOSPHORIC ACID 60% in WATER
Hexafluorophosphoricacid,60-70%
Phosphate(1-), hexafluoro-, hydrogen
Hexafluorophosphoric acid, 65% aqueous solution
HEXAFLUOROPHOSHORIC ACID
HEXAFLUOROPHOSPHORIC ACID: 60-65% AQUEOUS SOLUTION
HEXAFLUOROPHOSPHORIC ACID: CA. 65% AQUEOUS SOLUTION
Hexafluorophosphoric acid, ca 60% w/w aq. soln. | [EINECS(EC#)]
241-006-5 | [Molecular Formula]
F6HP | [MDL Number]
MFCD00011350 | [Molecular Weight]
145.97 | [MOL File]
16940-81-1.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless to slightly brown liquid (aqueous solution) | [Melting point ]
10 °C | [density ]
1.651 g/mL at 25 °C
| [storage temp. ]
2-8°C | [solubility ]
reacts with H2O | [form ]
Fuming Solution | [color ]
Colorless or slightly colored | [Stability:]
Stable. Incompatible with strong oxidizing agents. | [Water Solubility ]
hydrolyzes slowly | [Exposure limits]
ACGIH: TWA 0.5 ppm(2.5 mg/m3); Ceiling 2 ppm (Skin)
OSHA: TWA 3 ppm
NIOSH: IDLH 30 ppm(250 mg/m3); TWA 3 ppm(2.5 mg/m3); Ceiling 6 ppm(5 mg/m3) | [Uses]
Metal cleaners, electrolytic or chemical polishing agents for the formation of protective coatings
for metal surfaces, and as a catalyst. | [CAS DataBase Reference]
16940-81-1(CAS DataBase Reference) | [EPA Substance Registry System]
16940-81-1(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T+,T,C | [Risk Statements ]
R26/27/28:Very Toxic by inhalation, in contact with skin and if swallowed .
R35:Causes severe burns.
R34:Causes burns.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S7/9:Keep container tightly closed and in a well-ventilated place .
S36/37:Wear suitable protective clothing and gloves . | [RIDADR ]
UN 1782 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
SY7115000 | [Hazard Note ]
Corrosive/Toxic | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
28111990 | [Hazardous Substances Data]
16940-81-1(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
A clear colorless aqueous solution containing 60 percent hydrogen hexafluorophosphate (HPF6) by mass. Density 1.65 g/cm3. Corrosive to metals and tissue. | [Reactivity Profile]
HEXAFLUOROPHOSPHORIC ACID(16940-81-1) reacts exothermically with chemical bases (examples: amines, amides, and inorganic hydroxides). These reactions can generate dangerously large amounts of heat in small spaces. Dilution may generate significant heat. Reacts with active metals, including such structural metals as aluminum and iron, to release hydrogen, a flammable gas. Can initiate the polymerization of certain alkenes. Reacts with cyanide compounds to release gaseous hydrogen cyanide. Generates flammable and/or toxic gases in contact with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and strong reducing agents. Additional gas-generating reactions occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), and carbonates. May catalyze (increase the rate of) chemical reactions. | [Air & Water Reactions]
Fumes in air. Soluble in water with release of heat. | [Hazard]
Strong irritant to tissue. | [Health Hazard]
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. | [Fire Hazard]
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. | [Chemical Properties]
colourless to slightly brown liquid (aqueous solution) |
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