ChemicalBook--->CAS DataBase List--->4403-90-1

4403-90-1

4403-90-1 Structure

4403-90-1 Structure
IdentificationBack Directory
[Name]

Acid Green 25
[CAS]

4403-90-1
[Synonyms]

d&cgreen
CI 61570
MIDORI201
d&cgreen5
d&cgreen8
Green GS
CI NO 61570
D&CGREENNO.5
C Green No.5
ACID GREEN 25
zelenkysela25
c.i.acidgreen25
ALIZARIN GREEN G
Covalene Green GS
Basovit Green 876
Acid Fast Green G
Elbenyl Green B-BN
Weak Acid Green GS
QUINIZARIN GREEN S
D AND C GREEN NO 5
Acid Green 25, pure
Acid Green 25 (C.I.)
Sandoian Green MF-BL
NEUTER BRIGHT GREEN GS
Turquoise Green W7003.
ALIZARIN CYANINE GREEN
alizariancyaminegreenb
AilzarinbrilliantgreenG
ANTHRAQUINONE GREEN GNN
ALIZARIN CYANIN GREEN F
alizarin cyanin green g
Acid Brilliant Green GS
Kayanol Cyanine Green G
Dycosweak Acid Green GS
Neutral Cyanine Green GK
ALIZARIN CYANONE GREEN B
ALIZARIN CYANINE GREEN G
ALIZARINE CYANIN GREEN G
Naphthazine Fast Green GS
Chrome Anthraquinone Green
acid green 25 (C.I. 61570)
Ailzaringreen(C.1.No.61570)
abcolalizarinecyaninegreeng
Alizarine Brilliant Green G
Suminol Fast Cyanine Green G
Weak Acid Brilliant Green GS
ALIZARIN CYANONE GREEN B EXTRA
zelenalizarinovabrilantnig-extra
ALIZARIN CYANINE GREEN(Acid Green 25) C.I. No 61570
disodium 2,2-(anthraquinone-1,4-diimino)bis(5-methylsulphonate)
Dinatrium-2,2′-(9,10-dioxoanthracen-1,4-diyldiimino)bis(5-methylsulfonat
2,2’-(1,4-anthraquinonylenediimino)bis(5-methyl-benzenesulfonicacidisodiu
2,2’-(1,4-anthraquinonylenediimino)bis(5-methylbenzenesulfonicacid)disodium
disodium 2,2'-(9,10-dioxoanthracene-1,4-diyldiimino)bis(5-methylsulphonate)
D & C GREEN NO. 5, C.I.61570 (MIT FDA-ZERTIFIKAT) PULVER WASSERLOESLICH
2,2'-(1,4-Anthraquinonylenediimino)bis(5-methylbenzenesulfonic acid) disodium salt
Benzenesulfonic acid, 2,2'-(1,4-anthraquinonylenediimino)bis(5-methyl-, disodium salt
Disodiumsaltof2,2’-[9,10-dihydro-9,10-dioxo-1,4-anthracenediyl)diimino]bis-[5-methylbenzenesulfonicacid]
Benzenesulfonic acid, 2,2-(9,10-dihydro-9,10-dioxo-1,4-anthracenediyl)diiminobis5-methyl-, disodium salt
Disodium salt of 2,2'-[9,10-dihydro-9,10-dioxo-1,4-anthracenediyl) diimino]bis-[5-methylbenzenesulfonic acid
Disodium salt of 2,2'-[9,10-dihydro-9,10-dioxo-1,4-anthracenediyl)diimino]bis-[5-methylbenzenesulfonic acid]
[EINECS(EC#)]

224-546-6
[Molecular Formula]

C28H20N2Na2O8S2
[MDL Number]

MFCD00001193
[MOL File]

4403-90-1.mol
[Molecular Weight]

622.58
Chemical PropertiesBack Directory
[Appearance]

dark green powder
[Melting point ]

235-238 °C(lit.)
[storage temp. ]

room temp
[Colour Index ]

61570
[form ]

neat
[color ]

Bluish green powder
[Water Solubility ]

36 g/L (20 ºC)
[ε(extinction coefficient)]

≥10000 at 604-612nm
≥10200 at 640-646nm
≥20000 at 281-287nm
≥22700 at 251-257nm
≥6400 at 407-413nm
[λmax]

608 nm
642 nm (2nd)
[Merck ]

14,252
[Henry's Law Constant]

3.1×1023 mol/(m3Pa) at 25℃, HSDB (2015)
[Major Application]

diagnostic assay manufacturing
hematology
histology
[Cosmetics Ingredients Functions]

COLORANT
[InChIKey]

FPAYXBWMYIMERV-UHFFFAOYSA-L
[SMILES]

[Na+].[Na+].Cc1ccc(Nc2ccc(Nc3ccc(C)cc3S([O-])(=O)=O)c4C(=O)c5ccccc5C(=O)c24)c(c1)S([O-])(=O)=O
[LogP]

-1.966 at 20℃
[EPA Substance Registry System]

Benzenesulfonic acid, 2,2'-[(9,10-dihydro-9, 10-dioxo-1,4-anthracenediyl) diimino]bis[5-methyl-, disodium salt(4403-90-1)
Hazard InformationBack Directory
[Chemical Properties]

dark green powder
[Uses]

For nylon sutures: Fed. Regist. 42, 52395 (1977). Permitted for use in drugs and cosmetics, excluding use in eye area: ibid. 47, 49628 (1982).
[General Description]

Fine black or green powder.
[Air & Water Reactions]

Slightly soluble in water.
[Reactivity Profile]

Acid Green 25 is incompatible with strong oxidizing agents. .
[Fire Hazard]

Flash point data for Acid Green 25 are not available. Acid Green 25 is probably combustible.
[Preparation]

(a) ?anthracene-1,4,9,10-tetraol?or 1,4-Dihydroxyanthracene-9,10-dione and anthracene-1,4,9,10-tetraol?mixture?with 2 moles of p-Methylaniline in the presence of boric acid condensation; (b) 1,4-Dichloroanthracene-9,10-dione and 2 Moore’s p-Methylaniline?condensation, its product (C.I. Solvent Green 3, C.I. 61565) products, and translate into sodium salt.
[Flammability and Explosibility]

Nonflammable
[Safety Profile]

Moderately toxic by ingestion. Askin and severe eye irritant.
When heated to decomposition it emits very toxic fumesof NOx, SOx, and Na2O.
[Properties and Applications]

blue light green. Green powder. Soluble in water, no solution at room temperature gather the tendency. Soluble in o-chlorophenol, slightly soluble in acetone, ethanol, Pyridine, insoluble in chloroform, toluene. The strong sulfuric acid dyes shows blackish green color, diluted Tracy turn blue; In nitric acid are brown. The little blue water solution, and a blue hydrochloric acid; Add sodium hydroxide is blue light green. Used for wool, polyamide, silk and their blended fabric dyeing and printing. Can also be used in leather, paper, cosmetics, soap, wood, electrical-controlled aluminum and biological color.
Standard Light Fastness Soaping Persperation Fastness Oxygen bleaching Fastness to seawater
Fading Stain Fading Stain Fading Stain
ISO 6 3 2 4 2 1 4 3-4
AATCC 5 4 4 3 3 3 4 4
[Purification Methods]

Purify it by salting out three times from an aqueous solution with sodium acetate, followed by repeated extraction with EtOH [McGrew & Schneider J Am Chem Soc 72 2547 1950]. It is a green powder that is slightly soluble in Me2CO, EtOH and pyridine. It is soluble in conc H2SO4 to give a blue solution that becomes turquoise on dilution. [Allen et al. J Org Chem 7 63 1942, Beilstein 14 H 725.]
Safety DataBack Directory
[Symbol(GHS) ]

Environment (GHS09)
GHS09
[Signal word ]

Warning
[Hazard statements ]

H411
[Precautionary statements ]

P273
[Hazard Codes ]

N
[Risk Statements ]

51/53-36
[Safety Statements ]

24/25-61-26
[RIDADR ]

UN 3077 9 / PGIII
[WGK Germany ]

2
[RTECS ]

DB5044000
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HS Code ]

32041200
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Aquatic Chronic 2
[Hazardous Substances Data]

4403-90-1(Hazardous Substances Data)
[Toxicity]

LD50 orl-rat: >10 g/kg GTPZAB 28(7),53,84
Raw materials And Preparation ProductsBack Directory
[Raw materials]

1,4-Dihydroxyanthraquinone-->p-Toluidine-->1,4-Dichloroanthraquinone-->1,4-Dichloroanthraquinone-->Solvent Green 3-->1,4-Dihydroxyanthraquinone-->p-Toluidine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Acid Green 25(4403-90-1).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Acid Green 25(4403-90-1)FT-IR
Acid Green 25(4403-90-1)IR
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