| Identification | More | [Name]
Trifluoromethylthiobenzene | [CAS]
456-56-4 | [Synonyms]
ALPHA,ALPHA,ALPHA-TRIFLUOROTHIOANISOLE
PHENYL TRIFLUOROMETHYL SULFIDE
PHENYL TRIFLUOROMETHYL SULPHIDE
TRIFLUOROMETHYL PHENYL SULFIDE
(TRIFLUOROMETHYLTHIO)BENZENE
[(Trifluoromethyl)sulfanyl]benzene
Benzene, [(trifluoromethyl)thio]-
Trifluoromethyl phenyl sulphide~(Trifluoromethylthio)benzene~alpha,alpha,alpha-Trifluorothioanisole
Phenyl trifluoromethyl sulphide 98%
Phenyltrifluoromethylsulphide98% | [EINECS(EC#)]
207-270-0 | [Molecular Formula]
C7H5F3S | [MDL Number]
MFCD00040839 | [Molecular Weight]
178.17 | [MOL File]
456-56-4.mol |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) . | [RIDADR ]
UN 1993 3/PG 3
| [WGK Germany ]
3
| [Hazard Note ]
Toxic/Stench | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29309090 |
| Hazard Information | Back Directory | [Uses]
Phenyl trifluoromethyl sulfide may be used in the preparation of:
- sulfoxides, dithiane dioxide, and dithiolane dioxide via iron-catalyzed oxidation of sulfides, dithiane, or dithiolane with hydrogen peroxide
- benzophenone hydrazone derivatives
- trifluoro- and difluoromethylsilanes by reductive coupling of fluoromethyl sulfones, sulfoxides and sulfides with chlorosilanes
| [Synthesis Reference(s)]
The Journal of Organic Chemistry, 50, p. 4047, 1985 DOI: 10.1021/jo00221a017
Synthesis, p. 721, 1975 DOI: 10.1055/s-1975-23905 | [General Description]
Phenyl trifluoromethyl sulfide (PTFMS) is an aryl trifluoromethyl sulfide. PTFMS with (triethylgermyl)sodium forms a reagent system that has been employed for the trifluoromethylation of certain imines. The reaction between OH radical and PTFMS has been analyzed using pulse radiolysis technique and quantum chemical calculations. |
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