ChemicalBook--->CAS DataBase List--->462-34-0

462-34-0

462-34-0 Structure

462-34-0 Structure
IdentificationMore
[Name]

Boron trifluoride tetrahydrofuran complex
[CAS]

462-34-0
[Synonyms]

BORON TRIFLUORIDE TETRAHYDROFURAN COMPLEX
trifluoro(tetrahydrofuran)boron
BORON TRIFLUORIDE TETRAHYDROFURANE
Boron, trifluoro(tetrahydrofuran)-, (T-4)-
Boron trifluoride tetrahydrofuran complex 95%
Borontrifluoridetetrahydrofurancomplex95%
Trifluor(tetrahydrofuran)bor
[EINECS(EC#)]

207-325-9
[Molecular Formula]

C4H8BF3O
[MDL Number]

MFCD00040372
[Molecular Weight]

139.91
[MOL File]

462-34-0.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[Melting point ]

11-13 °C (lit.)
[Boiling point ]

180 °C (lit.)
[density ]

1.268 g/mL at 25 °C(lit.)
[vapor pressure ]

11Pa
[Fp ]

198 °F
[storage temp. ]

Store below +30°C.
[solubility ]

Miscible with dimethyl formamide.
[form ]

liquid
[explosive limit]

2.3-17.7%(V)
[Water Solubility ]

hydrolysis
[Sensitive ]

Moisture Sensitive
[InChI]

InChI=1S/C4H8BF3O/c6-5(7,8)9-3-1-2-4-9/h1-4H2
[InChIKey]

XYMZNNGTHKHCJH-UHFFFAOYSA-N
[SMILES]

[B+3](O1CCCC1)([F-])([F-])[F-]
[CAS DataBase Reference]

462-34-0(CAS DataBase Reference)
[EPA Substance Registry System]

462-34-0(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS05,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H302+H332-H314-H373
[Precautionary statements ]

P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338-P314
[Hazard Codes ]

C,T
[Risk Statements ]

R34:Causes burns.
R48/23:Toxic: danger of serious damage to health by prolonged exposure through inhalation .
R35:Causes severe burns.
R20/22:Harmful by inhalation and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

1
[Hazard Note ]

Toxic/Corrosive
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29321900
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Skin Corr. 1B
STOT RE 1 Inhalation
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Boron trifluoride tetrahydrofuran complex(462-34-0).msds
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liqui
[Uses]

Reactant or reagent involved in:
  • Deoxofluorination of alcohols and carbonyls
  • Synthesis of methacrylate-PEG-methacrylate-boron trifluoride self-doped gel polymer electrolytes
  • Hydroboration-oxidation of divinylferrocene

Reagent involved in the synthesis of biologically active molecules such as:
  • NK1 receptor antagonists
  • Complex polyketide natural products
  • Selective serotonin reuptake inhibitors
[Flammability and Explosibility]

Nonflammable
[reaction suitability]

core: boron
reagent type: Lewis acid
reagent type: catalyst
[Synthesis]

CN202010573013.3 provides a method of preparing a boron trifluoride tetrahydrofuran complex, said method of preparation enables instantaneous complexation of tetrahydrofuran and boron trifluoride, is able to avoid oxidative discoloration of tetrahydrof

Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Boron trifluoride tetrahydrofuran complex, 50%(462-34-0)
[Alfa Aesar]

Boron trifluoride-tetrahydrofuran complex, 95%(462-34-0)
[Sigma Aldrich]

462-34-0(sigmaaldrich)
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