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475-20-7

475-20-7 Structure

475-20-7 Structure
IdentificationMore
[Name]

(+)-LONGIFOLENE
[CAS]

475-20-7
[Synonyms]

(1R,2S,7S,9S)-3,3,7-TRIMETHYL-8-METHYLENETRICYCLO[5.4.0.0(2.9)]UNDECANE
(+)-LONGIFOLENE
LONGIFOLENE
LONGIFOLENE, (+)-
(+)-Longifolen
(+)-Longofolene
[1S-(1alpha,3abeta,4alpha,8abeta)]-decahydro-4,8,8-trimethyl-9-methylene-1,4-Methanoazulene
[1S-(1α,3aβ,4α,8aβ)]-decahydro-9-methylene-4,8,8-trimethyl-1,4-methanoazulene
1,4-Methanoazulene, decahydro-4,8,8-trimethyl-9-methylene-
1,4-Methanoazulene, decahydro-4,8,8-trimethyl-9-methylene-, (1S,3aR,4S,8aS)-(+)-
1,4-methanoazulene,decahydro-4,8,8-trimethyl-9-methylene-,(1s,3ar,4s,8as)-(
1,4-methanoazulene,decahydro-4,8,8-trimethyl-9-methylene-,(1S,3aR,4S,8aS)-(+)-
1,4-Methanoazulene,decahydro-4,8,8-trimethyl-9-methylene-,[1S-(1.alpha.,3a.beta.,4.alpha.,8a.beta.)]-
1,4-methanoazulene,decahydro-4,8,8-trimethyl-9-methylene-,[1s-(1alpha,3abet
1,4-methanoazulene,decahydro-9-methylene-4,8,8-trimethyl-,(1s-(1-alpha,3a-bet
4-Methanoazulene,decahydro-4,8,8-trimethyl-9-methylene-,[1S-(1.alpha.,3a.beta.,4.alpha.,8a.beta.)]1
4-Methanoazulene,decahydro-4,8,8-trimethyl-9-methylene-1
8a-beta))-4-alpha
8abeta)]-4alpha
Decahydro-4,8,8-trimethyl-9-methylene-1,4-methanoazulene
[EINECS(EC#)]

207-491-2
[Molecular Formula]

C15H24
[MDL Number]

MFCD00082306
[Molecular Weight]

204.35
[MOL File]

475-20-7.mol
Chemical PropertiesBack Directory
[alpha ]

D18 +42.73°
[Boiling point ]

254 °C706 mm Hg(lit.)
[density ]

0.928 g/mL at 25 °C(lit.)
[vapor pressure ]

5.3Pa at 24℃
[refractive index ]

n20/D 1.504(lit.)
[Fp ]

98 °C
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Sparingly)
[form ]

Oil
[color ]

Colourless to Pale Yellow
[Odor]

at 100.00 %. sweet woody rose medical fir needle
[Odor Type]

woody
[Optical Rotation]

+44.225 (c 4.6, CHCl3)
[Water Solubility ]

7.9mg/L at 24℃
[Merck ]

13,5588
[Stability:]

Light Sensitive
[Major Application]

food and beverages
[Cosmetics Ingredients Functions]

SKIN CONDITIONING - MISCELLANEOUS
FRAGRANCE
PERFUMING
[InChI]

1S/C15H24/c1-10-11-6-7-12-13(11)14(2,3)8-5-9-15(10,12)4/h11-13H,1,5-9H2,2-4H3/t11?,12?,13?,15-/m0/s1
[InChIKey]

PDSNLYSELAIEBU-WOFVOEOOSA-N
[SMILES]

CC1(C)CCC[C@]2(C)C3CCC(C13)C2=C
[LogP]

5 at 25℃
[CAS DataBase Reference]

475-20-7(CAS DataBase Reference)
[EPA Substance Registry System]

Longifolene (475-20-7)
Safety DataBack Directory
[Symbol(GHS) ]

Health Hazard (GHS08)Exclamation Mark (GHS07)Environment (GHS09)
GHS08,GHS07,GHS09
[Signal word ]

Warning
[Hazard statements ]

H304-H410-H317
[Precautionary statements ]

P273-P391-P501-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501
[RIDADR ]

UN1230 - class 3 - PG 2 - Methanol, solution
[WGK Germany ]

2
[RTECS ]

PB7724500
[F ]

8-10-23
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HS Code ]

29021990
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Aquatic Acute 1
Aquatic Chronic 1
Asp. Tox. 1
Skin Sens. 1
Hazard InformationBack Directory
[Description]

(+)-Longifolene is a kind of natural spice extracted from heavy turpentine. It has special chemical activity and is the raw material of synthetic resin, synthetic spice, flotation agent and organic synthesis. Also Longifolene can be used in the formulation of  flavors to replace some expensive flavors.
[Chemical Properties]

(+)-Longifolene is a kind of natural spice extracted from heavy turpentine. It has special chemical activity and is the raw material of synthetic resin, synthetic spice, flotation agent and organic synthesis. Also Longifolene can be used in the formulation of  flavors to replace some expensive flavors.
[Uses]

(+)-Longifolene is a tricyclic sesquiterpene, and the content in masson pine heavy turpentine is about 60%~78%. It has special chemical activity and can be used a raw material for synthetic resins, synthetic fragrances, flotation agents and organic synthesis.
[Definition]

ChEBI: (+)-longifolene is a longifolene. It is an enantiomer of a (-)-longifolene.
[Production Methods]

Longifolene is obtained by distillation, e.g., Indian turpentine.
[Synthesis Reference(s)]

[1] Wolfgang Oppolzer; Thierry Godel. A new and efficient total synthesis of (.+-.)-longifolene. J. Am. Chem. Soc. 1978, 100, 8, 2583–2584.
[Flammability and Explosibility]

Notclassified
[Synthesis]

In 1978, Wolfgang Oppolzer reported a new and efficient total synthesis of (+)-LONGIFOLENE[1]
( )-LONGIFOLENE
( )-LONGIFOLENE
Spectrum DetailBack Directory
[Spectrum Detail]

(+)-LONGIFOLENE(475-20-7)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

475-20-7(sigmaaldrich)
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