| Identification | Back Directory | [Name]
(R)-DIFLUORPHOS(TM) | [CAS]
503538-70-3 | [Synonyms]
(S)-DIFLUORPHOS(TM)
(R)-DIFLUORPHOS(TM)
R-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE
S-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-2,2,2',2'-TETRAFLUORO-4,4'-BI-1,3-BENZODIOXOLE
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97%
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloroMethane adduct (S)-DIFLUORPHOS
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole,dichloromethaneadduct,min.97%(S)-DIFLUORPHOS
S-(+)-5,5'-Bis(diphenylphosphino)-2,2,2',2'-tetrafluoro-4,4'-bi-1,3-benzodioxole, dichloromethane adduct, min. 97% (S)-DIFLUORPHOS(TM) | [Molecular Formula]
C38H24F4O4P2 | [MDL Number]
MFCD05861607 | [MOL File]
503538-70-3.mol | [Molecular Weight]
682.54 |
| Chemical Properties | Back Directory | [Boiling point ]
670.9±55.0 °C(Predicted) | [form ]
Powder | [color ]
white | [Sensitive ]
air sensitive | [InChIKey]
HGMLTMOEYCQDDR-UHFFFAOYSA-N | [SMILES]
O1C2=CC=C(P(C3=CC=CC=C3)C3=CC=CC=C3)C(C3=C4C(=CC=C3P(C3=CC=CC=C3)C3=CC=CC=C3)OC(F)(F)O4)=C2OC1(F)F | [CAS DataBase Reference]
503538-70-3 |
| Questions And Answer | Back Directory | [Reaction]
- Ligand used for the enantioselective hydrogenation of olefins, and especially electron-poor ketones.
- Ligand used for the enantioselective α-arylation of ketones.
- Ligand used for enantioselective alkylative aldol reactions.
- Nickel-catalyzed asymmetric α-heteroarylation of ketones with chloroarenes.
- Palladium-catalyzed asymmetric intramolecular arylation of α-keto amides.
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| Hazard Information | Back Directory | [Uses]
(S)-DIFLUORPHOS is an electron-poor diphosphane, and can also be used as a chiral supporting ligand.Also, used in preparation of chiral Amino Acid Esters and deuterated Amino Acid Esters. |
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| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
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400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
LaaJoo
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021-60702684 18516024827 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList20079/0_EN.htm |
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