| Identification | Back Directory | [Name]
TRIS(TRIPHENYLPHOSPHINEGOLD)OXONIUM TETRAFLUOROBORATE | [CAS]
53317-87-6 | [Synonyms]
TRIS(TRIPHENYLPHOSPHINEGOLD)OXONIUM TET&
Oxotris((triphenylphosphine)gold) tetrafluoroborate
Oxotris(triphenylphosphine)trigold tetrafluoroborate
TRIS(TRIPHENYLPHOSPHINEGOLD)OXOIUM TETRAFLUOROBORATE
TRIS(TRIPHENYLPHOSPHINEGOLD)OXONIUM TETRAFLUOROBORATE
Tris(triphenylphosphineaurio)oxonium tetrafluoroborate
TRIS[TRIPHENYLPHOSPHINEGOLD (I)]OXONIUM TETRAFLUOROBORATE
Tris[triphenylphosphinegold(I)]oxoniumtetrafluoroborate,98%
Tris[(triphenylphosphino)aurio(I)]oxonium tetrafluoroborate | [Molecular Formula]
C54H45Au3BF4OP3 | [MDL Number]
MFCD06658141 | [MOL File]
53317-87-6.mol | [Molecular Weight]
1480.56 |
| Chemical Properties | Back Directory | [Melting point ]
207°C (dec.) | [form ]
Powder | [color ]
off-white | [Sensitive ]
air sensitive | [InChI]
1S/3C18H15P.3Au.BF4.O/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;2-1(3,4)5;/h3*1-15H;;;;;/q;;;;;;-1;+1 | [InChIKey]
HTZIGJMQHZNAQD-UHFFFAOYSA-N | [SMILES]
[Au][O+]([Au])[Au].F[B-](F)(F)F.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9 |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for the Claisen Rearrangement of propargyl vinyl ethers. Chirality is efficiently transferred.
- Catalyst for the oxidative cleavage of a Carbon-Carbon triple bond in (Z)-Enynols and cyclization.
|
| Hazard Information | Back Directory | [Uses]
Used in a variety of gold catalyzed reactions including propargyl Claisen rearrangements. | [reaction suitability]
core: gold
reagent type: catalyst |
|
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Sigma-Aldrich
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https://www.sigmaaldrich.cn |
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Alfa Chemistry
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https://www.alfa-chemistry.com |
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Energy Chemical
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http://www.energy-chemical.com |
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