ChemicalBook--->CAS DataBase List--->53402-10-1

53402-10-1

53402-10-1 Structure

53402-10-1 Structure
IdentificationBack Directory
[Name]

(1R)-(-)-THIOCAMPHOR
[CAS]

53402-10-1
[Synonyms]

(1R)-(-)-THIOCAMPHOR
(1R)-(-)-Thiocamphor
(1R,4R)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2-thione
(1r)-(-)-1,7,7-trimethylbicyclo[2.2.1]heptane-2-thione
Bicyclo[2.2.1]heptane-2-thione, 1,7,7-trimethyl-, (1R,4R)-
[Molecular Formula]

C10H16S
[MDL Number]

MFCD00074855
[MOL File]

53402-10-1.mol
[Molecular Weight]

168.3
Chemical PropertiesBack Directory
[Melting point ]

136-138 °C(lit.)
[Boiling point ]

228-230 °C(lit.)
[density ]

0.9691 (rough estimate)
[refractive index ]

1.6500 (estimate)
[form ]

powder to crystal
[color ]

Light yellow to Brown
Safety DataBack Directory
[Hazard Codes ]

F,Xi
[Risk Statements ]

11-36/37/38
[Safety Statements ]

16-26-36
[RIDADR ]

UN 1325 4.1/PG 3
[WGK Germany ]

3
[HS Code ]

2930.90.9250
[HazardClass ]

4.1
[PackingGroup ]

III
Hazard InformationBack Directory
[Purification Methods]

It forms red prisms from EtOH and sublimes under vacuum. It possesses a sulfurous odour and is volatile like camphor. [Sen J Indian Chem Soc 12 647 1935, Sen J Indian Chem Soc 18 76 1941.] The racemate crystallises from *C6H6 and has m 145o [138.6-139o, White & Bishop J Am Chem Soc 62 10 1940]. [Beilstein 7 III 419.]
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