ChemicalBook--->CAS DataBase List--->546-56-5

546-56-5

546-56-5 Structure

546-56-5 Structure
IdentificationMore
[Name]

Octaphenylcyclotetrasiloxane
[CAS]

546-56-5
[Synonyms]

OCTAPHENYLCYCLOTETRASILOXANE
1,1,3,3,5,5,7,7-Octaphenylcyclotetrasiloxane
2,2,4,4,6,6,8,8-Octaphenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane
2,4,6,8-tetradiphenyl-[1,3,5,7,2,4,6,8]cyclotetrasiloxane
CO9817
Cyclotetrasiloxane, octaphenyl-
octaphenyl-cyclotetrasiloxan
octaphenylcylclotetrasiloxane
Octaphenyltetracyclosiloxane
OCTAPHENYLCYCLOTETRASILOXANE 99+%
Octaphenylcyclotetrasiloxane,98+%
2,2,4,4,6,6,8,8-Octaphenyl-1,3,5,7-tetraoxa-2,4,6,8-tetrasilacyclooctane
2,2,4,4,6,6,8,8-Octaphenylcyclooctanetetrasiloxane
[EINECS(EC#)]

208-904-9
[Molecular Formula]

C48H40O4Si4
[MDL Number]

MFCD00003268
[Molecular Weight]

793.17
[MOL File]

546-56-5.mol
Chemical PropertiesBack Directory
[Appearance]

White solid
[Melting point ]

196-198 °C(lit.)
[Boiling point ]

334 °C
[density ]

1.185
[vapor pressure ]

0Pa at 25℃
[refractive index ]

1.62
[Fp ]

200 °C
[storage temp. ]

Storage temp. 2-8°C
[solubility ]

very faint turbidity in Toluene
[form ]

solid
[color ]

White to Almost white
[Specific Gravity]

1.185
[Water Solubility ]

insoluble
[Hydrolytic Sensitivity]

1: no significant reaction with aqueous systems
[BRN ]

2320758
[LogP]

9 at 20℃
[CAS DataBase Reference]

546-56-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Octaphenylcyclotetrasiloxane(546-56-5)
[EPA Substance Registry System]

546-56-5(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302
[Precautionary statements ]

P280-P305+P351+P338
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

1
[RTECS ]

GZ4398500
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29319090
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Octaphenylcyclotetrasiloxane(546-56-5).msds
Questions And AnswerBack Directory
[Application]

Octaphenylcyclotetrasiloxane can be physically blended into antifouling coatings in monomer form to reduce the surface energy of the coating, increase the flexibility of the film, and also act as an antifoaming agent. An example of its application is as follows: A heat-dissipating coating is composed of the following raw material components in parts: 100-150 parts polyvinyl chloride, 78-80 parts polyether polyol, 80-85 parts polymethyl methacrylate, 55-80 parts polytetrafluoroethylene, 65-70 parts polyisoprene, 80-90 parts polypropylene, 6-10 parts alumina, 6-8 parts magnesium oxide, 4-6 parts octaphenylcyclotetrasiloxane, 6-8 parts sodium thiosulfate, and 7-9 parts dodecyl diisocyanate. The composition includes: methylamine acetylacetonate, 4-6 parts yttrium acetylacetonate, 5-8 parts 2-thiophenecarboxyltrifluoroacetone, 6-8 parts methyl methacrylate, 6-8 parts dibutyltin dilaurate, 8-10 parts quartz powder, 8-10 parts silica powder, 8-12 parts silica, 7-9 parts n-butanol, 3-5 parts dimethyl carbonate, 2-4 parts p-phenylenediamine, 3-5 parts stearoylbenzoylmethane, 4-5 parts triethyl phosphite, 8-10 parts titanium dioxide, and 12-15 parts bentonite. This invention's heat-dissipating coating exhibits excellent heat dissipation, good adhesion, strong stability, and is safe and free of toxic side effects.
Hazard InformationBack Directory
[Chemical Properties]

White solid
[Preparation]

Octaphenylcyclotetrasiloxane is typically produced industrially by one of two processes: 1) the hydrolysis of diphenyldichlorosilane or 2) the hydrolysis of diphenyldialkoxysilanes.
Process the production of octaphenylcyclotetrasiloxane
[Flammability and Explosibility]

Notclassified
[Purification Methods]

Recrystallise it from AcOH, EtOAc, *C6H6 or *C6H6/EtOH. It forms two stable isomorphs and both forms, as well as the mixture, melt at 200-201o. There is a metastable form which melts at 187-189o. [Burkhard et al. J Am Chem Soc 67 2174 1945, Hyde et al. J Am Chem Soc 69 488 1947, Beilstein 16 IV 1530.]
Spectrum DetailBack Directory
[Spectrum Detail]

Octaphenylcyclotetrasiloxane(546-56-5)MS
Octaphenylcyclotetrasiloxane(546-56-5)1HNMR
Octaphenylcyclotetrasiloxane(546-56-5)13CNMR
Octaphenylcyclotetrasiloxane(546-56-5)IR1
Octaphenylcyclotetrasiloxane(546-56-5)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Octaphenylcyclotetrasiloxane, 98%(546-56-5)
[Alfa Aesar]

Octaphenylcyclotetrasiloxane, 98+%(546-56-5)
[Sigma Aldrich]

546-56-5(sigmaaldrich)
[TCI AMERICA]

Octaphenylcyclotetrasiloxane,>98.0%(LC)(546-56-5)
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