ChemicalBook--->CAS DataBase List--->54655-07-1

54655-07-1

54655-07-1 Structure

54655-07-1 Structure
IdentificationBack Directory
[Name]

LITHIUM (TRIMETHYLSILYL)ACETYLIDE
[CAS]

54655-07-1
[Synonyms]

solution0.5MinTHF
(TRIMETHYLSILYL)ETHYNYLLITHIUM
Lithio(trimethylsilyl)acetylene
2-(Trimethylsilyl)ethynyllithium
Lithium trimethylsilylacetylenide
LITHIUM (TRIMETHYLSILYL)ACETYLIDE
1-Lithio-2-(trimethylsilyl)acetylene
LithiuM,[2-(triMethylsilyl)ethynyl]-
Lithium (trimethylsilyl) acetylide in THF
Lithium (trimethylsilyl)acetylide solution
LITHIUM (TRIMETHYLSILYL)ACETYLIDE SOL., ~0.5 M IN THF
Lithium (trimethylsilyl)acetylide, 0.5m solution in THF
LithiuM (triMethylsilyl)acetylide solution 0.5 M in THF
LITHIUM (TRIMETHYLSILYL)ACETYLIDE, 0.5M IN TETRAHYDROFURAN
Lithium (trimethylsilyl)acetylide, 0.5M solution in THF/Hexane
Lithium (trimethylsilyl)acetylide0.5M solution in THFAcroSeal§3
LithiuM(triMethylsilyl)acetylide, 0.5 M solution in THF, SpcSeal
Lithium (trimethylsilyl)acetylide, 0.5M solution in THF, AcroSeal
LITHIUM (TRIMETHYLSILYL)ACETYLIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
LithiuM (triMethylsilyl)acetylide, 0.5M solution in THF, AcroSeal 100ML
lithium (trimethylsilyl)acetylide, 0.5m in tetrahydrofuran (12-13 wt %)
[Molecular Formula]

C5H9LiSi
[MDL Number]

MFCD00075059
[MOL File]

54655-07-1.mol
[Molecular Weight]

104.15
Chemical PropertiesBack Directory
[Appearance]

clear yellow to orange solution
[density ]

0.829 g/mL at 25 °C
[Fp ]

−10 °F
[storage temp. ]

Flammables area
[form ]

Solution
[color ]

Clear yellow to orange
[Specific Gravity]

0.829
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[BRN ]

3587411
[InChI]

1S/C5H9Si.Li/c1-5-6(2,3)4;/h2-4H3;
[InChIKey]

ZVXXEONXFWSCIZ-UHFFFAOYSA-N
[SMILES]

[Li]C#C[Si](C)(C)C
Hazard InformationBack Directory
[Chemical Properties]

clear yellow to orange solution
[Uses]

Reacts with halotriazines to produce conductive, anisotropic carbon-nitrogen materials.1
[Preparation]

Lithium (trimethylsilyl)acetylide is most often prepared in situ by treatment of Trimethylsilylacetylene with n-Butyllithium, Lithium Diisopropylamide, or Ethyllithium-Lithium Bromide. It can also be prepared by monodesilylation of Bis(trimethylsilyl)acetylene with MeLi-LiBr complex (see Methyllithium).
Safety DataBack Directory
[Hazard Codes ]

F,C,Xn
[Risk Statements ]

11-19-34-36/37/38-40
[Safety Statements ]

16-26-36/37/39-45-36/37
[RIDADR ]

UN 2924 3/PG 2
[WGK Germany ]

1
[F ]

10-21
[TSCA ]

No
[HS Code ]

29310099
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Carc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
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