| Identification | More | [Name]
9-Bromophenanthrene | [CAS]
573-17-1 | [Synonyms]
9-BROMOPHENANTHRENE
9-bromo-phenanthren
9-Phenanthryl bromide
9-Phenathryl bromide
9-phenathrylbromide
9-Bromophenanthrene,97%
9-Bromophenathrene
9-Bromophenanthrene,95%
Phenanthrene, 9-bromo-
9-Bromoanth raceme 96% | [EINECS(EC#)]
209-351-6 | [Molecular Formula]
C14H9Br | [MDL Number]
MFCD00001174 | [Molecular Weight]
257.13 | [MOL File]
573-17-1.mol |
| Chemical Properties | Back Directory | [Appearance]
light yellow powder | [Melting point ]
60-64 °C (lit.) | [Boiling point ]
180-190 °C/2 mmHg (lit.) | [density ]
1.4251 (rough estimate) | [refractive index ]
1.6404 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
chloroform: 50 mg/mL, clear
| [form ]
Powder | [color ]
Light yellow | [BRN ]
1869927 | [InChI]
InChI=1S/C14H9Br/c15-14-9-10-5-1-2-6-11(10)12-7-3-4-8-13(12)14/h1-9H | [InChIKey]
RSQXKVWKJVUZDG-UHFFFAOYSA-N | [SMILES]
C1=C2C(C3C(C(Br)=C2)=CC=CC=3)=CC=C1 | [CAS DataBase Reference]
573-17-1(CAS DataBase Reference) | [NIST Chemistry Reference]
Phenanthrene, 9-bromo-(573-17-1) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [RTECS ]
SF7197000
| [F ]
8 | [Hazard Note ]
Irritant | [HS Code ]
29036990 |
| Hazard Information | Back Directory | [Description]
9-Bromophenanthrene is a luminescent material that fluoresces at short wavelengths and can be used as a molecular probe to detect the presence of other compounds and the mechanism of reaction, among other things. | [Chemical Properties]
light yellow powder | [Uses]
9-Bromophenanthrene is used as halogenated building block. Isotope labelled 9-Bromophenanthrene (B687200), a halogenated polycyclic aromatic hydrocarbon that has been seen to have a room temperature phosphorescence that can be induced by β-cyclodextrin (β-CD) in the presence of cyclohexane; however, trace Fe(III) causes a decrease of the RTP emission. | [Preparation]
9-Bromophenanthrene (90-94%) is produced by adding bromine to a refluxing solution of phenanthrene in carbon tetrachloride. This is the starting-point of 9-substituted phenanthrenes, e.g, when heated with cuprous cyanide at 260℃, 9-bromophenanthrene forms the corresponding cyano-compound; this may be hydrolysed to phenanthrene-9-carboxylic acid. Phenanthrene undergoes the Friedel-Crafts reaction mainly in the 3-, and to a small extent, in the 2-position. It is chloromethylated in the 9-position. When nitrated, phenanthrene gives a mixture of three mononitro-derivatives, the 3-isomer predominating. Sulphonation of phenanthrene gives a mixture of 1-, 2-, 3- and 9-phenanthrenesulphonic acids, and the ratio of these isomers depends on the temperature. |
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