| Identification | More | [Name]
2-HYDROXYACETOPHENONE | [CAS]
582-24-1 | [Synonyms]
2-HYDROXYACETOPHENONE
ALPHA-HYDROXYACETOPHENONE
BENZOYLCARBINOL
PHENACYL ALCOHOL
RARECHEM AL BD 0384
2-hydroxy-1-phenyl-ethanon
2-Hydroxy-1-phenylethanone
2-Hydroxyethylphenyl ketone
Acetophenone, 2-hydroxy-
Acetophenone, alpha-hydroxy-
Ethanone, 2-hydroxy-1-phenyl-
Glycolophenone
Methanol, benzoyl-
omega-Hydroxyacetophenone
2-hydroxy-1-phenylethan-1-one
2-Hydroxyacetophenone,97+%
ALPHA-HYDROXYACETOPHENONE/2-HYDROXYACETOPHENONE
2-HYDROXY ACETOPHENONE98%MIN
2-hydroxy-1-ethanone
Hydroxymethyl phenyl ketone | [EINECS(EC#)]
209-480-8 | [Molecular Formula]
C8H8O2 | [MDL Number]
MFCD00041829 | [Molecular Weight]
136.15 | [MOL File]
582-24-1.mol |
| Chemical Properties | Back Directory | [Appearance]
slightly yellow to orange powder | [Melting point ]
86-89 °C (lit.) | [Boiling point ]
126 °C / 12mmHg | [density ]
1.0963 | [refractive index ]
1.5470 (estimate) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Powder | [pka]
13.09±0.10(Predicted) | [color ]
Slightly yellow to orange | [Water Solubility ]
Soluble in water, ether, ethanol, chloroform. | [Sensitive ]
Air & Moisture Sensitive | [InChI]
1S/C8H8O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,9H,6H2 | [InChIKey]
ZWVHTXAYIKBMEE-UHFFFAOYSA-N | [SMILES]
OCC(=O)c1ccccc1 | [LogP]
0.721 (est) | [CAS DataBase Reference]
582-24-1(CAS DataBase Reference) | [NIST Chemistry Reference]
«alpha»-Hydroxyacetophenone(582-24-1) | [EPA Substance Registry System]
582-24-1(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
29144000 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
slightly yellow to orange powder | [Uses]
2-Hydroxyacetophenone can be used as a starting material for the synthesis of:
- Enantioselective 1R-phenyl-1,2-ethanediol in the presence of a rhodium(III) catalyst by asymmetric transfer hydrogenation.
- Copper(II) complexes of 2-hydroxyacetophenone N-substituted thiosemicarbazones.
- Chromium, molybdenum, and ruthenium complexes of 2-hydroxyacetophenone Schiff bases.
- 2-Hydroxyacetophenone-aroyl hydrazone derivatives for inhibition of copper corrosion in nitric acid.
| [Uses]
2-Hydroxyacetophenone can be used to produce 2-hydroxy-1-phenyl-ethanone-(1)-oxime by heating. It is used as pharmaceutical intermediate. | [Definition]
ChEBI: A monohydroxyacetophenone that is acetophenone in which one of the methyl hydrogens has been replaced by a hydroxy group. | [Synthesis]
Add 20 mmol of 48% hydrobromic acid to a 500 mL three-necked flask containing 20 mmol of styrene and 100 mL of water at room temperature, and slowly add 200 mmol of .
30% hydrogen peroxide, control the drip time for 30min, stir at room temperature for 30m | [IC 50]
HIV |
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