| Identification | More | [Name]
Chloroiodomethane | [CAS]
593-71-5 | [Synonyms]
CHLOROIODOMETHANE
METHYLENE CHLOROIODIDE
Methane, chloroiodo-
CHLOROIODOMETHANE, STAB.
Chloroiodomethane,98%
Chloroiodomethane, stabilized, 98%
CHLOROIODOMETHANE , STABILIZED WITH COPPER
Chloroiodomethane, 98%, stab. with copper
Chloroiodomethane (stabilized with Copper chip)
Chloroiodomethane, stabilized with copper, 97+%
Chloroiodomethane, 98%, stabilized | [EINECS(EC#)]
209-804-8 | [Molecular Formula]
CH2ClI | [MDL Number]
MFCD00001078 | [Molecular Weight]
176.38 | [MOL File]
593-71-5.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR PALE YELLOW TO PINK-REDDISH LIQUID | [Boiling point ]
108-109 °C (lit.) | [density ]
2.422 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.582(lit.)
| [Fp ]
108-109°C | [storage temp. ]
0-6°C | [solubility ]
Miscible with acetone, benzene, diethyl ether and alcohol. | [form ]
Liquid | [color ]
Clear pale yellow to pink-reddish | [Specific Gravity]
2.422 | [Sensitive ]
Light Sensitive | [BRN ]
1730802 | [Henry's Law Constant]
8.4×10-3 mol/(m3Pa) at 25℃, Burkholder et al. (2019) | [Stability:]
Volatile | [InChI]
1S/CH2ClI/c2-1-3/h1H2 | [InChIKey]
PJGJQVRXEUVAFT-UHFFFAOYSA-N | [SMILES]
ClCI | [CAS DataBase Reference]
593-71-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Chloroiodomethane(593-71-5) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS06 | [Signal word ]
Danger | [Hazard statements ]
H301-H315-H319-H335 | [Precautionary statements ]
P261-P264-P270-P301+P310-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) . | [RIDADR ]
UN2810 | [WGK Germany ]
3
| [F ]
8 | [REACH Registrations]
Active | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29034980 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Description]
Chloroiodomethane is a halogenated hydrocarbon that has been studied for its photolytic properties. For instance, the photolysis of chloroiodomethane in cryogenic matrices along with recombination of the nascent radical pair was studied. | [Chemical Properties]
CLEAR PALE YELLOW TO PINK-REDDISH LIQUID | [Uses]
Chloroiodomethane is used as an intermediate in pharmaceuticals, organic synthesis, agrochemicals and dyestuff. It is also useful in cyclopropanation (Simmon-Smith reaction), Mannich reaction, aminomethylation and in epoxidation. | [General Description]
The photolysis of chloroiodomethane in cryogenic matrices along with recombination of the nascent radical pair was studied. | [Solubility in organics]
Miscible with acetone, benzene, diethyl ether and alcohol. |
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