| Identification | More | [Name]
Trifluoromethyl iodide | [CAS]
2314-97-8 | [Synonyms]
IODOTRIFLUOROMETHANE
PERFLUOROMETHYL IODIDE
TRIFLUOROMETHYL IODIDE
CF3I
CIF3
Freon13I1
freon13t1
iodotrifluoromethane(trifluoromethyliodide)
Methane,trifluoroiodo-
monoiodotrifluoromethane
R13I1
Trifluoriodmethan
Trifluoriodomethane
trifluoroiodo-methan
TRIFLUOROMETHYL IODIDE CYLINDER WITH
Trifluoromethyliodide,min.97%
Iodotrifluoromethane 99%
Iodotrifluoromethane99%
Trifluoroiodomethane, 99.9%
Trifluoroiodomethane, 97+% | [EINECS(EC#)]
219-014-5 | [Molecular Formula]
CF3I | [MDL Number]
MFCD00001060 | [Molecular Weight]
195.91 | [MOL File]
2314-97-8.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless gas | [Melting point ]
<−78 °C(lit.)
| [Boiling point ]
−22.5 °C(lit.)
| [density ]
2.361 | [vapor pressure ]
540.5kPa at 25℃ | [refractive index ]
1.379 | [Fp ]
-22.5°C | [form ]
Gas | [Stability:]
Stable. Substances to be avoided include strong oxidizing agents. Avoid direct sunlight. Risk of explosion if heated under confinement. Flammable. | [Water Solubility ]
Slightly soluble in water. | [Sensitive ]
Light Sensitive | [BRN ]
1732740 | [CAS DataBase Reference]
2314-97-8(CAS DataBase Reference) | [NIST Chemistry Reference]
Methane, trifluoroiodo-(2314-97-8) | [EPA Substance Registry System]
2314-97-8(EPA Substance) |
| Questions And Answer | Back Directory | [Uses]
Trifluoroiodomethane is used as a gaseous fire suppression flooding agent for in-flight aircraft and electronic equipment fires. It is also an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It is involved in the rhodium-catalyzed alfa-trifluoromethylation of alfa,beta-unsaturatedketones. It plays an important role as catalyst in the enantioselective alfa -trifluoromethylation of aldehydes through photoredox organocatalysis using a readily available iridium photocatalyst.
| [Reactions]
Trifluoromethyl iodide reacts with [AuMeL] to give [AuMe2(CF3)L] and [AuIL](L = PMe3 or PMe2Ph), or [Au(CF3)L] and Mel (L = PPh3), or a mixture of these products (L = PMePh2). In some cases reaction of [AuMe(PMe3)] with CF3I gives [AuMe(CF3)I(PMe3)]. Evidence is presented that the reactions proceed, at least in part, by a free-radical chain mechanism.
|
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R68:Possible risk of irreversible effects. | [Safety Statements ]
S36/37:Wear suitable protective clothing and gloves . | [RIDADR ]
UN 1956 2.2
| [WGK Germany ]
1
| [RTECS ]
PB6975000
| [F ]
27 | [Hazard Note ]
Irritant | [TSCA ]
T | [HazardClass ]
2.2 |
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