ChemicalBook--->CAS DataBase List--->6002-34-2

6002-34-2

6002-34-2 Structure

6002-34-2 Structure
IdentificationBack Directory
[Name]

TERT-BUTYLDIPHENYLPHOSPHINE
[CAS]

6002-34-2
[Synonyms]

NSC 244302
TERT-BUTYLDIPHENYLPHOSPHINE
Diphenyl(tert-butyl)phosphine
tert-butyl(diphenyl)phosphane
tert-Butyldiphenylphosphine 97%
(1,1-Dimethylethyl)diphenylphosphine
Phosphine,(1,1-dimethylethyl)diphenyl-
[EINECS(EC#)]

227-848-6
[Molecular Formula]

C16H19P
[MDL Number]

MFCD00015004
[MOL File]

6002-34-2.mol
[Molecular Weight]

242.3
Chemical PropertiesBack Directory
[Melting point ]

52-55 °C(lit.)
[Boiling point ]

144-146 °C2 mm Hg(lit.)
[Fp ]

>230 °F
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

crystal
[color ]

white
[InChI]

InChI=1S/C16H19P/c1-16(2,3)17(14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3
[InChIKey]

QZUPHAGRBBOLTB-UHFFFAOYSA-N
[SMILES]

P(C(C)(C)C)(C1=CC=CC=C1)C1=CC=CC=C1
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
[Signal word ]

Warning
[Hazard statements ]

H301-H315-H319
[Precautionary statements ]

P280-P301+P310-P305+P351+P338-P362-P405-P501A
[Risk Statements ]

22-36/37/38
[Safety Statements ]

26-37
[WGK Germany ]

3
[TSCA ]

No
[Storage Class]

10 - Combustible liquids
Hazard InformationBack Directory
[Uses]

New family of Ph2(t-Bu)P phosphines for efficient Silyl-Heck transformations.
[Definition]

ChEBI: NSC 244302 is a member of benzenes.
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings
Spectrum DetailBack Directory
[Spectrum Detail]

TERT-BUTYLDIPHENYLPHOSPHINE(6002-34-2)1HNMR
TERT-BUTYLDIPHENYLPHOSPHINE(6002-34-2)31PNMR
TERT-BUTYLDIPHENYLPHOSPHINE(6002-34-2)13CNMR
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