| Identification | More | [Name]
ETHYLDIPHENYLPHOSPHINE | [CAS]
607-01-2 | [Synonyms]
DIPHENYLETHYLPHOSPHINE ETHYLDIPHENYLPHOSPHINE Ethyldiphenylphosphine,98% Ethyldiphenylphosphine,99% Silicagel, functionalized, Diphenylphosphinoethyl, 0.7 mmol/g (Diphenylphosphino)ethane 1-(Diphenylphosphino)ethane | [EINECS(EC#)]
627-386-9 | [Molecular Formula]
C14H15P | [MDL Number]
MFCD00015170 | [Molecular Weight]
214.24 | [MOL File]
607-01-2.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless liquid | [Boiling point ]
293 °C(lit.) | [density ]
1.048 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.614(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Liquid | [color ]
Clear colorless | [Specific Gravity]
1.048 | [Sensitive ]
Air Sensitive | [BRN ]
744253 | [InChI]
InChI=1S/C14H15P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3 | [InChIKey]
WUOIAOOSKMHJOV-UHFFFAOYSA-N | [SMILES]
P(CC)(C1=CC=CC=C1)C1=CC=CC=C1 | [CAS DataBase Reference]
607-01-2(CAS DataBase Reference) | [EPA Substance Registry System]
Phosphine, ethyldiphenyl- (607-01-2) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed. R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [RIDADR ]
3278 | [WGK Germany ]
3
| [RTECS ]
SY9242500
| [F ]
10-13-23 | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29310099 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Acute Tox. 4 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless liquid | [Uses]
Catalyst for:
- Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide
- Regio- and stereoselective hydroalkynylation of methylenecyclopropanes
- Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles
- Dimer to monomer conversion
- Tandem Morita-Baylis-Hillman/Michael addition reactions
- Platinum-catalyzed cyclization
- Regioselective and stereoselective [3+2] cycloaddition
- Platinum-catalyzed intermolecular hydroamination
- Hydroformylation reactions
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand |
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