ChemicalBook--->CAS DataBase List--->609-66-5

609-66-5

609-66-5 Structure

609-66-5 Structure
IdentificationMore
[Name]

2-Chlorobenzamide
[CAS]

609-66-5
[Synonyms]

2-CHLOROBENZAMIDE
O-CHLORO-BENZAMIDE
TIMTEC-BB SBB004023
2-chloro-benzamid
o-chloro-benzamid
2-Chlorobenzamide o-Chlorobenzamide
2-Chlorobenzamide,97%
2-Chlorbenzamid
Benzamide, o-chloro
[EINECS(EC#)]

210-195-6
[Molecular Formula]

C7H6ClNO
[MDL Number]

MFCD00007973
[Molecular Weight]

155.58
[MOL File]

609-66-5.mol
Chemical PropertiesBack Directory
[Appearance]

ALMOST WHITE CRYSTALLINE POWDER
[Melting point ]

142-144 °C(lit.)
[Boiling point ]

275.0±23.0 °C(Predicted)
[density ]

1.2187 (rough estimate)
[refractive index ]

1.5618 (estimate)
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

powder to crystal
[pka]

15.36±0.50(Predicted)
[color ]

White to Almost white
[BRN ]

508510
[InChI]

1S/C7H6ClNO/c8-6-4-2-1-3-5(6)7(9)10/h1-4H,(H2,9,10)
[InChIKey]

RBGDLYUEXLWQBZ-UHFFFAOYSA-N
[SMILES]

NC(=O)c1ccccc1Cl
[CAS DataBase Reference]

609-66-5(CAS DataBase Reference)
[EPA Substance Registry System]

609-66-5(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/22:Harmful by inhalation and if swallowed .
[Safety Statements ]

S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

1
[RTECS ]

CV2443737
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

IRRITANT
[HS Code ]

2924297099
[Storage Class]

13 - Non Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Raw materials And Preparation ProductsBack Directory
[Raw materials]

2-Chlorobenzoyl chloride-->Ammonia
[Preparation Products]

chlorbenzuron-->2-Chlorobenzoyl isocyanate-->2-Chlorobenzylamine-->2-Chloro-1,4-benzoquinone-->5-(2-Chlorophenyl)-1H-tetrazole-->N-Benzyl-2-chlorobenzaMide, 97%
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Chlorobenzamide(609-66-5).msds
Hazard InformationBack Directory
[Chemical Properties]

ALMOST WHITE CRYSTALLINE POWDER
[Uses]

2-Chlorobenzamide is used to synthesize chlortetracycline and o-chlorobenzoyl isocyanate, which is an intermediate in chlortetracycline synthesis.
[General Description]

2-Chlorobenzamide is the major degradation product of CCU (1-(2-chlorobenzoyl)-3-(4-chlorophenyl) urea), a new insect growth regulator. It undergoes room temperature Pd-mediated hydrodehalogenations with KF and polymethylhydrosiloxane (PMHS) to yield benzamide. t undergoes reduction with NaBH4 in diglyme at 162°C to yield 2-chlorobenzonitrile.
[Synthesis]

Prepared by reacting o-chlorobenzoyl chloride with ammonia.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Chlorobenzamide(609-66-5)MS
2-Chlorobenzamide(609-66-5)1HNMR
2-Chlorobenzamide(609-66-5)13CNMR
2-Chlorobenzamide(609-66-5)IR1
2-Chlorobenzamide(609-66-5)IR2
2-Chlorobenzamide(609-66-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Chlorobenzamide, 98%(609-66-5)
[Alfa Aesar]

2-Chlorobenzamide, 98%(609-66-5)
[Sigma Aldrich]

609-66-5(sigmaaldrich)
[TCI AMERICA]

2-Chlorobenzamide,>98.0%(T)(609-66-5)
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