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612-83-9

612-83-9 Structure

612-83-9 Structure
IdentificationMore
[Name]

3,3'-Dichlorobenzidine dihydrochloride
[CAS]

612-83-9
[Synonyms]

3,3'-Dichloro(1,1'-biphenyl)-4,4'-diamine dihydrochloride
3,3'-DICHLORO-4,4'-BIPHENYLDIAMINE DIHYDROCHLORIDE
3,3'-DICHLORO-4,4'-DIAMINODIPHENYL DIHYDROCHLORIDE
3,3'-DICHLOROBENZIDINE DIHYDROCHLORIDE
3,3-DICHLOROBENZIDINE DIHYDROCHLORIDE
4,4'-DIAMINO-3,3'-DICHLOROBIPHENYLDIHYDROCHLORIDE
1’-biphenyl)-4,4’-diamine,3,3’-dichloro-(dihydrochloride
1’-biphenyl]-4,4’-diamine,3,3’-dichloro-[dihydrochloride
3,3’-dichloro-benzidindihydrochloride
3,3-DICHLOROBENZIDINE DIHYD
3,3'-Dichlorobenzidine HCl
3,3'-DICHLOROBENZIDINE 2HCL
3,3'-Dichloro Benzidene Dihydrochloride
[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dichloro-, dihydrochloride
3, 3''-DICHLOROBENZIDINE DIHYDROCHLORIDE, 99.5%
3,3'-Dichlorobenzidine dihydrochloride
3,3'-Dichloro-4,4'-diaminobiphenyl dihydrochloride
4-(4-Amino-3-chlorophenyl)-2-chloroaniline dihydrochloride
3,3'-Dichlorobenzidine·2hydrochloride
[EINECS(EC#)]

210-323-0
[Molecular Formula]

C12H12Cl4N2
[MDL Number]

MFCD00040388
[Molecular Weight]

326.05
[MOL File]

612-83-9.mol
Chemical PropertiesBack Directory
[Appearance]

3,3’-Dichlorobenzidine is a gray or purple crystalline solid.
[Melting point ]

132~137℃
[solubility ]

Chloroform (Slightly), DMSO (Slightly, Heated), Methanol (Slightly, Heated)
[form ]

neat
[Stability:]

Stable, but may be air or light sensitive. Incompatible with strong oxidizing agents.
[Water Solubility ]

<0.1 g/100 mL at 21.5 ºC
[InChI]

InChI=1S/C12H10Cl2N2.ClH/c13-9-5-7(1-3-11(9)15)8-2-4-12(16)10(14)6-8;/h1-6H,15-16H2;1H
[InChIKey]

HXFNXEIKMAEASE-UHFFFAOYSA-N
[SMILES]

ClC1=C(C=CC(C2C=CC(N)=C(Cl)C=2)=C1)N.Cl
[LogP]

3.76 at 20℃
[CAS DataBase Reference]

612-83-9(CAS DataBase Reference)
[EPA Substance Registry System]

612-83-9(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R45:May cause cancer.
R21:Harmful in contact with skin.
R43:May cause sensitization by skin contact.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

3
[RTECS ]

DD0550000
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[Safety Profile]

Confirmed carcinogen. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits very toxic fumes of Cl and NOx.
[Hazardous Substances Data]

612-83-9(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Methanol-->Hydrazinium hydroxide solution-->Hydrazine hydrate-->1,4-Naphthoquinone
[Preparation Products]

Pigment Yellow 12
Hazard InformationBack Directory
[General Description]

Light tan powder.
[Reactivity Profile]

3,3'-DICHLOROBENZIDINE DIHYDROCHLORIDE(612-83-9) reacts as a weak acid. May react vigorously with strong oxidizing agents. May generate flammable gases with strong reducing agents.
[Air & Water Reactions]

Insoluble in water.
[Potential Exposure]

A halide-and amine-substituted aromatic compound used in the dye industry, curing agent for isocyanate terminated resins. The major uses of dichlorobenzidine are in the manufacture of pigments for printing ink, textiles, plastics, and crayons and as a curing agent for solid urethane plastics. There are no substitutes for many of its uses. Additional groups that may be at risk include workers in the printing or graphic arts professions handling the 3,3’-DCB-based azo pigments. 3,3’-DCB may be present as an impurity in the pigments, and there is some evidence that 3,3’-DCB may be metabolically liberated from the azo pigment
[Fire Hazard]

Flash point data for this compound are not available but 3,3'-DICHLOROBENZIDINE DIHYDROCHLORIDE is probably combustible.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required
[Incompatibilities]

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Achemical base: neutralize acids to form salts plus water with an exothermic reaction. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generatedby amines in combination with strong reducing agents such as hydrides, nitrides, alkali metals, and sulfides.
[Chemical Properties]

3,3’-Dichlorobenzidine is a gray or purple crystalline solid.
[Chemical Properties]

beige to tan powder
[Waste Disposal]

Incineration (816C, 0.5 second for primary combustion; 1204C, 1.0 second for secondary combustion). The formation of elemental chlorine can be prevented through injection of steam ormethane into the combustion process. nitrogen oxides may be abated through the use of thermal or catalytic devices. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal
[Uses]

3,3'-Dichlorobenzidine Dihydrochloride, is structurally similar to Benzidine (B121000), and thus is considered a carcinogen. It can be used in the production of azo dyes. Dyes and metabolites, Environmental Testing
[Flammability and Explosibility]

Nonflammable
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3,3'-Dichloro(1,1'-biphenyl)-4,4'-diamine dihydrochloride(612-83-9).msds
Spectrum DetailBack Directory
[Spectrum Detail]

3,3'-Dichlorobenzidine dihydrochloride(612-83-9)1HNMR
3,3'-Dichlorobenzidine dihydrochloride(612-83-9)IR1
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

612-83-9(sigmaaldrich)
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