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615-05-4

615-05-4 Structure

615-05-4 Structure
IdentificationMore
[Name]

2,4-DIAMINOANISOLE
[CAS]

615-05-4
[Synonyms]

2,4-DIAMINOANISOLE
3-AMINO-4-METHOXYANILINE
4-METHOXY-1,3-PHENYLENEDIAMINE
4-METHOXY-BENZENE-1,3-DIAMINE
4-METHOXY-M-PHENYLENEDIAMINE
1,3-benzenediamine,-methoxy-
1,3-Diamino-4-methoxybenzene
2,4 DAA
2,4daa
2,4-Diamineanisole
2,4-diamino-1-methoxy-benzen
2,4-Diamino-1-methoxybenzene
2,4-Diaminoanisol
2,4-diamino-anisol
2,4-Diaminoanisole base
2,4-diaminoanisole(anditssalts)
2,4-diaminoanisolebase
4-Methoxy-1,3-benzenediamine
4-methoxy-3-benzenediamine
4-methoxy-3-phenylenediamine
[EINECS(EC#)]

210-406-1
[Molecular Formula]

C7H10N2O
[MDL Number]

MFCD00007803
[Molecular Weight]

138.17
[MOL File]

615-05-4.mol
Chemical PropertiesBack Directory
[Appearance]

2,4-Diaminoanisole is a needle-like solid.
[Melting point ]

67.5°C
[Boiling point ]

253.57°C (rough estimate)
[density ]

1.1315 (rough estimate)
[refractive index ]

1.5200 (estimate)
[solubility ]

Chloroform (Slightly), DMSO (Slightly), Methanol (Very Slightly)
[Colour Index ]

76050
[form ]

neat
[pka]

5.19±0.10(Predicted)
[BRN ]

2085522
[CAS DataBase Reference]

615-05-4(CAS DataBase Reference)
[IARC]

2B (Vol. Sup 7, 79) 2001
[NIST Chemistry Reference]

1,3-Benzenediamine, 4-methoxy-(615-05-4)
[EPA Substance Registry System]

615-05-4(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R45:May cause cancer.
R22:Harmful if swallowed.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R68:Possible risk of irreversible effects.
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

2811
[WGK Germany ]

3
[RTECS ]

BZ8580500
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[Safety Profile]

Confirmed carcinogen. Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental reproductive effects. Human mutation data reported. A skin irritant. When heated to decomposition it emits toxic fumes of NOx. See also other diaminoanisole entries.
[Hazardous Substances Data]

615-05-4(Hazardous Substances Data)
Hazard InformationBack Directory
[General Description]

Colorless needles. Primarily used (along with salts such as 2,4-DIAMINOANISOLE(615-05-4) sulfate) as a component of hair & fur dye formulations.
[Reactivity Profile]

2,4-DIAMINOANISOLE is incompatible with the following: Strong oxidizers .
[Potential Exposure]

The principal use of 2,4-diamino-ani- sole (and its salts such as the sulfate) as a component of oxidation (permanent) hair and fur dye formulations. Human exposure to 2,4-diaminoanisole sulfate may possibly occur through skin absorption at chemical and dye production facilities, as well as through dermal contact in persons using hair dyes containing the chemical.
[First aid]

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respira- tion with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with run- ning water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical obser- vation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
[Shipping]

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
[Incompatibilities]

Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. The sulfate may react violently with aluminum and magnesium.
[Description]

2,4-Diaminoanisole is a needle-like solid.Molecular weight = 138.19; Freezing/Melting point67-68℃. The sulfate is an off-white to violet powder.Hazard Identification (based on NFPA-704 M RatingSystem): Health 3, Flammability 0, Reactivity 0 (includessulfate). Soluble in water.
[Chemical Properties]

2,4-Diaminoanisole is a needle-like solid.
[Waste Disposal]

Dissolve or mix the material with a combustible solvent and burn in a chemical incinera- tor equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed .
[Uses]

2,4-Diaminoanisole may be used as an analytical reference standard for the determination of the analyte in:
  • Mainstream waterpipe smoke using liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS).
  • Haircolor products by high performance liquid chromatography (HPLC).

[Definition]

ChEBI: 2,4-Diaminoanisole is a member of methoxybenzenes.
[storage]

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with 2,4-DAAsulfate you should be trained on its proper handling andstorage. A regulated, marked area should be establishedwhere this chemical is handled, used, or stored in compliance with OSHA Standard 1910.1045. Store in tightlyclosed containers in a cool, well-ventilated area away fromaluminum and magnesium.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-methoxy-m-phenylenediamine(615-05-4).msds
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

615-05-4(sigmaaldrich)
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