| Identification | More | [Name]
2,4-DIAMINOANISOLE | [CAS]
615-05-4 | [Synonyms]
2,4-DIAMINOANISOLE
3-AMINO-4-METHOXYANILINE
4-METHOXY-1,3-PHENYLENEDIAMINE
4-METHOXY-BENZENE-1,3-DIAMINE
4-METHOXY-M-PHENYLENEDIAMINE
1,3-benzenediamine,-methoxy-
1,3-Diamino-4-methoxybenzene
2,4 DAA
2,4daa
2,4-Diamineanisole
2,4-diamino-1-methoxy-benzen
2,4-Diamino-1-methoxybenzene
2,4-Diaminoanisol
2,4-diamino-anisol
2,4-Diaminoanisole base
2,4-diaminoanisole(anditssalts)
2,4-diaminoanisolebase
4-Methoxy-1,3-benzenediamine
4-methoxy-3-benzenediamine
4-methoxy-3-phenylenediamine | [EINECS(EC#)]
210-406-1 | [Molecular Formula]
C7H10N2O | [MDL Number]
MFCD00007803 | [Molecular Weight]
138.17 | [MOL File]
615-05-4.mol |
| Chemical Properties | Back Directory | [Appearance]
2,4-Diaminoanisole is a needle-like solid. | [Melting point ]
67.5°C | [Boiling point ]
253.57°C (rough estimate) | [density ]
1.1315 (rough estimate) | [refractive index ]
1.5200 (estimate) | [storage temp. ]
2-8°C | [solubility ]
Chloroform (Slightly), DMSO (Slightly), Methanol (Very Slightly) | [Colour Index ]
76050 | [form ]
neat | [pka]
5.19±0.10(Predicted) | [BRN ]
2085522 | [Major Application]
cleaning products
cosmetics
food and beverages
personal care | [InChI]
1S/C7H10N2O/c1-10-7-3-2-5(8)4-6(7)9/h2-4H,8-9H2,1H3 | [InChIKey]
BAHPQISAXRFLCL-UHFFFAOYSA-N | [SMILES]
COc1ccc(N)cc1N | [CAS DataBase Reference]
615-05-4(CAS DataBase Reference) | [IARC]
2B (Vol. Sup 7, 79) 2001 | [NIST Chemistry Reference]
1,3-Benzenediamine, 4-methoxy-(615-05-4) | [EPA Substance Registry System]
615-05-4(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N | [Risk Statements ]
R45:May cause cancer.
R22:Harmful if swallowed.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R68:Possible risk of irreversible effects. | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
2811 | [WGK Germany ]
3 | [RTECS ]
BZ8580500 | [TSCA ]
TSCA listed | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 4 Oral
Aquatic Chronic 2
Carc. 1B
Muta. 2 | [Safety Profile]
Confirmed carcinogen.
Poison by intraperitoneal route. Moderately
toxic by ingestion. Experimental
reproductive effects. Human mutation data
reported. A skin irritant. When heated to
decomposition it emits toxic fumes of NOx.
See also other diaminoanisole entries. | [Hazardous Substances Data]
615-05-4(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
Colorless needles. Primarily used (along with salts such as 2,4-DIAMINOANISOLE(615-05-4) sulfate) as a component of hair & fur dye formulations. | [Reactivity Profile]
2,4-DIAMINOANISOLE is incompatible with the following: Strong oxidizers . | [Potential Exposure]
The principal use of 2,4-diamino-ani-
sole (and its salts such as the sulfate) as a component of
oxidation (permanent) hair and fur dye formulations.
Human exposure to 2,4-diaminoanisole sulfate may
possibly occur through skin absorption at chemical and dye
production facilities, as well as through dermal contact in
persons using hair dyes containing the chemical. | [First aid]
Move victim to fresh air. Call 911 or emergency
medical service. Give artificial respiration if victim is not
breathing. Do not use mouth-to-mouth method if victim
ingested or inhaled the substance; give artificial respira-
tion with the aid of a pocket mask equipped with a one-way
valve or other proper respiratory medical device.
Administer oxygen if breathing is difficult. Remove and
isolate contaminated clothing and shoes. In case of contact
with substance, immediately flush skin or eyes with run-
ning water for at least 20 minutes. For minor skin contact,
avoid spreading material on unaffected skin. Keep victim
warm and quiet. Effects of exposure (inhalation, ingestion,
or skin contact) to substance may be delayed. Ensure that
medical personnel are aware of the material(s) involved
and take precautions to protect themselves. Medical obser-
vation is recommended for 24 to 48 hours after breathing
overexposure, as pulmonary edema may be delayed.
As first aid for pulmonary edema, a doctor or authorized
paramedic may consider administering a drug or other
inhalation therapy. | [Shipping]
UN2811 Toxic solids, organic, n.o.s., Hazard
Class: 6.1; Labels: 6.1-Poisonous materials, Technical
Name Required. UN3143 Dyes, solid, toxic, n.o.s. or Dye
intermediates, solid, toxic, n.o.s., Hazard Class: 6.1;
Labels: 6.1-Poisonous materials, Technical Name Required. | [Incompatibilities]
Incompatible with strong oxidizers
(chlorates, nitrates, peroxides, permanganates, perchlorates,
chlorine, bromine, fluorine, etc.); contact may cause fires
or explosions. Keep away from alkaline materials, strong
bases, strong acids, oxoacids, and epoxides. The sulfate
may react violently with aluminum and magnesium. | [Description]
2,4-Diaminoanisole is a needle-like solid.Molecular weight = 138.19; Freezing/Melting point67-68℃. The sulfate is an off-white to violet powder.Hazard Identification (based on NFPA-704 M RatingSystem): Health 3, Flammability 0, Reactivity 0 (includessulfate). Soluble in water. | [Chemical Properties]
2,4-Diaminoanisole is a needle-like solid. | [Waste Disposal]
Dissolve or mix the material
with a combustible solvent and burn in a chemical incinera-
tor equipped with an afterburner and scrubber. All federal,
state, and local environmental regulations must be
observed
. | [Uses]
2,4-Diaminoanisole may be used as an analytical reference standard for the determination of the analyte in:
- Mainstream waterpipe smoke using liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS/MS).
- Haircolor products by high performance liquid chromatography (HPLC).
| [Definition]
ChEBI: 2,4-Diaminoanisole is a member of methoxybenzenes. | [storage]
Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with 2,4-DAAsulfate you should be trained on its proper handling andstorage. A regulated, marked area should be establishedwhere this chemical is handled, used, or stored in compliance with OSHA Standard 1910.1045. Store in tightlyclosed containers in a cool, well-ventilated area away fromaluminum and magnesium. |
|
| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
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https://www.sigmaaldrich.cn |
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