| Identification | More | [Name]
2,2,2-Trifluoroethyl trifluoromethanesulfonate | [CAS]
6226-25-1 | [Synonyms]
2,2,2-TRIFLUOROETHYL TRIFLATE
2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULFONATE
2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULPHONATE
TFOL-TF
TRIFLUOROMETHANESULFONIC ACID 2,2,2-TRIFLUOROETHYL ESTER
2,2,2-trifluoroethyltrifluorometanesulfonicacid
methanesulfonicacid,trifluoro-,2,2,2-trifluoroethylester
2,2,2-Trifluoroethyl trifluoromethanesulphonate 97%
2,2,2-Trifluoroethyltrifluoromethanesulphonate97%
TRIFLUOROMETHANESULPHONICACID2,2,2-TRIFLUOROETHYLESTER | [EINECS(EC#)]
458-390-7 | [Molecular Formula]
C3H2F6O3S | [MDL Number]
MFCD00671579 | [Molecular Weight]
232.1 | [MOL File]
6226-25-1.mol |
| Chemical Properties | Back Directory | [Boiling point ]
89-91°C | [density ]
1,61 g/cm3 | [refractive index ]
1.3037 | [RTECS ]
PB2775000 | [Fp ]
>110°(230°F) | [storage temp. ]
2-8°C | [solubility ]
Chloroform, Methanol (Slightly) | [form ]
Liquid | [color ]
Colorless to yellow | [Water Solubility ]
Slightly soluble in water. | [Sensitive ]
Moisture Sensitive | [InChI]
InChI=1S/C3H2F6O3S/c4-2(5,6)1-12-13(10,11)3(7,8)9/h1H2 | [InChIKey]
RTMMSCJWQYWMNK-UHFFFAOYSA-N | [SMILES]
C(F)(F)(F)S(OCC(F)(F)F)(=O)=O | [CAS DataBase Reference]
6226-25-1(CAS DataBase Reference) | [EPA Substance Registry System]
6226-25-1(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS05,GHS06 | [Signal word ]
Danger | [Hazard statements ]
H301-H314-H330 | [Precautionary statements ]
P260-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | [Hazard Codes ]
Xi,T,C | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
3265 | [WGK Germany ]
3 | [Hazard Note ]
Irritant | [REACH Registrations]
Active | [HazardClass ]
8 | [HazardClass ]
TOXIC, CORROSIVE | [PackingGroup ]
Ⅱ | [HS Code ]
29055900 | [Storage Class]
6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials | [Hazard Classifications]
Acute Tox. 2 Inhalation
Acute Tox. 3 Oral
Skin Corr. 1B |
| Hazard Information | Back Directory | [Uses]
A fluorine-containing alkyl alkanesulfonate with cyctotoxity towards cultured leukemia L1210 cells. | [Synthesis]
In a 100-ml flask equipped with a stirrer, a thermometer, a nitrogen introducing pipe, and a condenser, 50 ml (0.297 mol) of trifluoromethane sulfonic anhydride and 25 ml (0.342 moles) of 2,2,2-trifluoroethanol were placed at room temperature and stirred for 30 minutes in a nitrogen atmosphere, followed by reflux for 3 hours. After distillation, 50.3 g of 2,2,2-trifluoroethyl trifluoromethanesulfonate was obtained in a yield of 73%.
 | [References]
[1] Patent: US2014/249162, 2014, A1. Location in patent: Paragraph 0423; 0424; 0425
[2] Patent: EP2781519, 2014, A1. Location in patent: Paragraph 0404; 0405; 0406
[3] Tetrahedron, 1988, vol. 44, # 17, p. 5375 - 5387
[4] Journal of Organic Chemistry, 1984, vol. 49, # 12, p. 2258 - 2273
[5] Journal of Fluorine Chemistry, 2016, vol. 192, p. 131 - 140 |
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