| Identification | More | [Name]
2-METHOXYETHYL CHLOROFORMATE | [CAS]
628-12-6 | [Synonyms]
2-METHOXYETHYL CHLOROFORMATE
CHLOROFORMIC ACID 2-METHOXYETHYL ESTER
ETHYLENE GLYCOL MONOMETHYL ETHER CHLOROFORMATE
2-Methoxyethyl chloroformate, tech. 85% | [EINECS(EC#)]
211-026-9 | [Molecular Formula]
C4H7ClO3 | [MDL Number]
MFCD00058932 | [Molecular Weight]
138.55 | [MOL File]
628-12-6.mol |
| Chemical Properties | Back Directory | [Boiling point ]
157-158 °C(lit.) | [density ]
1.192 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.4200(lit.)
| [Fp ]
138 °F
| [storage temp. ]
2-8°C | [solubility ]
Soluble in most organic solvents. | [form ]
clear liquid | [color ]
Colorless to Light yellow | [Sensitive ]
Moisture Sensitive | [InChI]
1S/C4H7ClO3/c1-7-2-3-8-4(5)6/h2-3H2,1H3 | [InChIKey]
NDYYWMXJZWHRLZ-UHFFFAOYSA-N | [SMILES]
COCCOC(Cl)=O | [CAS DataBase Reference]
628-12-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2920 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [HS Code ]
2918.99.5000 | [HazardClass ]
6.1 | [PackingGroup ]
II | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Dam. 1
Flam. Liq. 3
Skin Corr. 1B |
| Hazard Information | Back Directory | [Uses]
2-methoxyethyl chloroformate was used to produce di-2-dimethoxyethyl hydrazine carboxylate(alternative reagent for the mitsunobu reaction). | [Uses]
Reactant for:• ;Preparation of N-bridged bicyclic sulfonamides as inhibitors of γ-secretase1• ;Preparation of dimethoxyethyl azodicarboxylate via amidation/oxidation and application to Mitsunobu reaction2• ;Regioselective, stereoselective, and kinetically-controlled nickel-catalyzed cyanoesterification of allenes chloroformates and TMSCN3• ;Preparation of amino carboxamidobenzothiazoles as Lck inhibitors4• ;Preparation of nonracemic spirooxindoles using a stereoselective three-component coupling reaction as the key step and using acylation reactions to add st |
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J & K SCIENTIFIC LTD.
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Alfa Aesar
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Energy Chemical
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Maya High Purity Chemicals
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Sigma-Aldrich
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BePharm Ltd
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