| Identification | More | [Name]
n-Tridecane | [CAS]
629-50-5 | [Synonyms]
ALKANE C13
N-TRIDECANE
TRIDECANE
Tridecane, n-
TRIDECANE, STANDARD FOR GC
N-TRIDECANE, 1000MG, NEAT
N-TRIDECANE OEKANAL
TRIDECANE, 99+%
N-TRIDECANE MIN. 99,9 % FOR GAS CHROMATO GRAPHY
N-Tridecane>99%
N-Tridecane~98%
standardmaterial
Tridecan
TRIDECANE,N-(SG)
1-TRIDECANE
NAPHTHOCAINE
n-Tridecan
N-TRIDECANE WITH GC
Tridecane [Standard Material] | [EINECS(EC#)]
211-093-4 | [Molecular Formula]
C13H28 | [MDL Number]
MFCD00008979 | [Molecular Weight]
184.36 | [MOL File]
629-50-5.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless liquid | [Melting point ]
-6--4 °C (lit.) | [Boiling point ]
110-112 °C/12 mmHg (lit.)
234 °C (lit.) | [density ]
0.756 g/mL at 25 °C(lit.)
| [vapor density ]
6.4 (vs air)
| [vapor pressure ]
1 mm Hg ( 59.4 °C)
| [refractive index ]
n20/D 1.425(lit.)
| [Fp ]
215 °F
| [storage temp. ]
Store below +30°C. | [form ]
Liquid | [color ]
Clear colorless | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents. | [explosive limit]
0.6-6.5%(V) | [Water Solubility ]
PRACTICALLY INSOLUBLE | [Specific Heat Capacity]
Cp(liquid):406.7J/(g·K),at 25℃ | [Thermal Conductivity]
0.131 W/(m·K) at 25 ℃ | [BRN ]
1733089 | [Henry's Law Constant]
3.4×10-6 mol/(m3Pa) at 25℃, Duchowicz et al. (2020) | [Major Application]
petroleum | [Cosmetics Ingredients Functions]
SKIN CONDITIONING - EMOLLIENT | [InChI]
1S/C13H28/c1-3-5-7-9-11-13-12-10-8-6-4-2/h3-13H2,1-2H3 | [InChIKey]
IIYFAKIEWZDVMP-UHFFFAOYSA-N | [SMILES]
CCCCCCCCCCCCC | [LogP]
7.331 (est) | [Surface tension]
24.79mN/m at 293.15K | [Uses]
Organic synthesis, distillation chaser. | [CAS DataBase Reference]
629-50-5(CAS DataBase Reference) | [NIST Chemistry Reference]
Tridecane(629-50-5) | [EPA Substance Registry System]
Tridecane (629-50-5) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS08 | [Signal word ]
Danger | [Hazard statements ]
H304 | [Precautionary statements ]
P301+P310-P331-P405-P501 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [RTECS ]
YD3025000
| [Autoignition Temperature]
>204 °C | [TSCA ]
Yes | [REACH Registrations]
Active | [HS Code ]
29011090 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Asp. Tox. 1 | [Hazardous Substances Data]
629-50-5(Hazardous Substances Data) | [Toxicity]
LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rat > 2000 mg/kg |
| Hazard Information | Back Directory | [General Description]
An oily straw yellow clear liquid with a hydrocarbon odor. Flash point 190-196°F. Specific gravity 0.76. Boiling point 456°F. Repeated or prolonged skin contact may irritate or redden skin, progressing to dermatitis. Exposure to high concentrations of vapor may result in headache and stupor. | [Reactivity Profile]
Saturated aliphatic hydrocarbons, such as TRIDECANE(629-50-5), may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, they burn exothermically to produce carbon dioxide and water. | [Air & Water Reactions]
Insoluble in water. | [Health Hazard]
May be harmful by inhalation, ingestion or skin absorption. Vapor or mist is irritating to the eyes, mucous membrane and upper respiratory tract. Causes skin irritation. | [Chemical Properties]
colourless liquid | [Application]
Tridecane serves not only as an industrial fuel or organic solvent, but also as an emollient in skincare and cosmetic products. It helps to keep the skin moisturised, soothe the skin and improve its texture, whilst not clogging the pores, making it suitable for those with oily, combination and sensitive skin. | [Definition]
ChEBI: Tridecane is a straight chain alkane containing 13 carbon atoms. It forms a component of the essential oils isolated from plants such as Abelmoschus esculentus. It has a role as a plant metabolite and a volatile oil component. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 46, p. 3909, 1981 DOI: 10.1021/jo00332a030
Tetrahedron, 48, p. 8253, 1992 DOI: 10.1016/S0040-4020(01)80493-2 | [Safety Profile]
Moderately toxic by intravenousroute. When heated to decomposition it emits acrid smokeand irritating fumes. | [Preparation]
Tridecane (n-Tridecane) was synthesised by reacting C13-condensed (1,5-bis(2-furanyl)-1,4-pentadien-3-one) as the starting material, with acetone as the solvent and Pt/Al₂O₃ as the catalyst, for 24 hours at 493 K and 5.5 MPa. The yield exceeded 22%. The general mechanism of its synthesis is as follows:
it is a sequence of four steps with different catalysts at different reaction conditions: the hydrolysis of the sugar polymers; followed by the dehydration of sugars yielding aldehydes; the con densation of these compounds using a linking molecule (usually acetone); and the total hydrodeoxygenation of these condensation adducts to the final lineal hydrocarbons, with similar properties as the mineral diesel[1].
 | [Synthesis]
n-Tridecane is obtained by petrochemical refining. | [Carcinogenicity]
Mice treated with tridecane
developed tumors on their backs, after exposure to ultraviolet
radiation at wavelengths longer than 350 nm, generally
considered noncarcinogenic. | [storage]
Store at -20°C | [References]
[1] Laura Faba. (2016). Hydrodeoxygenation of furfural-acetone condensation adducts to tridecane over platinum catalysts. Catalysis Today, 269, Pages 132-139. https://doi.org/10.1016/j.cattod.2015.09.055 |
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