ChemicalBook--->CAS DataBase List--->638-38-0

638-38-0

638-38-0 Structure

638-38-0 Structure
IdentificationMore
[Name]

MANGANESE(II) ACETATE
[CAS]

638-38-0
[Synonyms]

MANGANESE ACETATE
MANGANESE (II) 2,4-PENTANEDIONATE
MANGANESE(II) ACETATE
Aceticacid,manganese(2+)salt
aceticacid,manganese(ii)salt(2:1)
diacetylmanganese
manganese(2+)acetate
manganeseacetate(mn(oac)2)
manganesediacetate
manganousacetate
octanmanganaty
octanmanganaty(czech)
Manganeseacetateanhydrous
ManganeseAcetateTetrahydrateExtraPure
Manganese(II) acetate, anhydrous, 98+%
manganese(ii) acetate, anhydrous
acetic acid, manganese salt
Bisacetic acid manganese(II) salt
Bisacetoxymanganese(II)
Diacetic acid manganese(II)
[EINECS(EC#)]

211-334-3
[Molecular Formula]

C4H6MnO4
[MDL Number]

MFCD00013039
[Molecular Weight]

173.03
[MOL File]

638-38-0.mol
Chemical PropertiesBack Directory
[Appearance]

Pale red crystals
[Melting point ]

180°C
[density ]

1.589
[vapor pressure ]

13hPa at 25℃
[storage temp. ]

Store below +30°C.
[form ]

Powder
[color ]

Grayish-beige to light brown
[Water Solubility ]

Soluble in water, methanol and acetic acid.
[Sensitive ]

Hygroscopic
[Merck ]

13,5746
[Exposure limits]

OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
[InChI]

InChI=1S/2C2H4O2.Mn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
[InChIKey]

NKKRYPIWDQMINN-UHFFFAOYSA-M
[SMILES]

C(=O)(C)O[Mn]OC(=O)C
[Uses]

Textile dyeing, oxidation catalyst, paint and varnish (drier, boiled oil manufacture), fertilizers, food packaging, feed additive.
[CAS DataBase Reference]

638-38-0(CAS DataBase Reference)
[EPA Substance Registry System]

Acetic acid, manganese(2+) salt (638-38-0)
Safety DataBack Directory
[Symbol(GHS) ]

Health Hazard (GHS08)
GHS08
[Signal word ]

Warning
[Hazard statements ]

H373-H412
[Precautionary statements ]

P260-P273-P314-P501
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R40:Limited evidence of a carcinogenic effect.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[WGK Germany ]

3
[RTECS ]

AI5770000
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29152990
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Aquatic Chronic 3
STOT RE 2 Inhalation
[Hazardous Substances Data]

638-38-0(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Acetic acid-->Adipic acid-->Terephthalic acid-->Trimellitic Anhydride-->Isovaleric acid-->Manganese(II) acetate tetrahydrate
Hazard InformationBack Directory
[Description]

Manganese (II) acetate is the chemical compound with the formula Mn(CH3COO)2. It is used as a desiccant, a catalyst, and as fertilizer.
[Chemical Properties]

Pale-red crystals.Soluble in water and alcohol. Combustible.
[Reactions]

Manganese (II) acetate can be formed by reacting acetic acid with either manganese (II,III) oxide or manganese (II) carbonate :
Mn3O4 + 2CH3COOH → Mn(CH3COO)2 + Mn2O3+ H2O
If manganese (II,III) oxide is used , manganese (III) oxide is produced as a byproduct.
If the anhydrous form needs to be produced, manganese (II) nitrate can be reacted with acetic anhydride.
[reaction suitability]

core: manganese
[Purification Methods]

Crystallise it from water acidified with acetic acid. [Beilstein 2 IV 120.]
Spectrum DetailBack Directory
[Spectrum Detail]

MANGANESE(II) ACETATE(638-38-0)MS
MANGANESE(II) ACETATE(638-38-0)IR1
MANGANESE(II) ACETATE(638-38-0)IR2
MANGANESE(II) ACETATE(638-38-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Manganese(II) acetate, anhydrous, 98+%(638-38-0)
[Alfa Aesar]

Manganese(II) acetate, anhydrous, 98+%(638-38-0)
[Sigma Aldrich]

638-38-0(sigmaaldrich)
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