ChemicalBook--->CAS DataBase List--->546-89-4

546-89-4

546-89-4 Structure

546-89-4 Structure
IdentificationMore
[Name]

Lithium acetate
[CAS]

546-89-4
[Synonyms]

ACETIC ACID LITHIUM SALT
LITHIUM ACETATE
LITHIUM ACETATE PHIX(R) BUFFER
Lithiumacetat
lithiumethanate
Lithiumethanoat
lithiumethanoate
quilone
LITHIUM ACETATE SOLUTION 5M
LITHIUM ACETATE, 99.99%
LithiumAcetateGr(Dihydrate)
LithiumAcetateDihydrate,>96%
LithiumAcetateDihydrateA.R.
Lithiumacetatehydrate,Puratronic,99.998%(metalsbasis)
Lithium acetate, pure
lithium acetate solution
LITHIUMACETATE,CRYSTAL,REAGENT
Lithium acetate hydrate, Puratronic(R), 99.998% (metals basis)
Acetic acid lithium
[EINECS(EC#)]

208-914-3
[Molecular Formula]

C2H3LiO2
[MDL Number]

MFCD00013057
[Molecular Weight]

65.99
[MOL File]

546-89-4.mol
Chemical PropertiesBack Directory
[Appearance]

solid
[Melting point ]

283-285 °C (lit.)
[density ]

1.3[at 20℃]
[vapor pressure ]

0Pa at 25℃
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

H2O: 5 M at 20 °C, clear, colorless
[form ]

Powder or Crystals
[color ]

White to yellow
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Water Solubility ]

40.8 g/100 mL (20 ºC)
[Merck ]

14,5521
[Major Application]

battery precursors
catalysts
material synthesis precursor
[InChI]

InChI=1S/C2H4O2.Li/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
[InChIKey]

XIXADJRWDQXREU-UHFFFAOYSA-M
[SMILES]

C([O-])(=O)C.[Li+]
[LogP]

0.09 at 25℃
[CAS DataBase Reference]

546-89-4(CAS DataBase Reference)
[EPA Substance Registry System]

546-89-4(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H319
[Precautionary statements ]

P264-P270-P280-P301+P312-P305+P351+P338-P337+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36:Irritating to the eyes.
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
S39:Wear eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S22:Do not breathe dust .
[WGK Germany ]

1
[RTECS ]

AI5450000
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29152990
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Irrit. 2
[Safety Profile]

Poison by intravenous route. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALUMINUM and LITHIUM COMPOUNDS.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Lithium hydroxide-->Lithium-->Silver acetate-->Ruthenium-->Acetic acid
[Preparation Products]

1-Iodobutane-->Lithium formate monohydrate-->Formaldehyde-->4-Nitrophenol-->METHYL 3-OXOHEPTANOATE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Acetic acid lithium salt(546-89-4).msds
Hazard InformationBack Directory
[Description]

Lithium acetate (CH3COOLi) is a salt of lithium and acetic acid (CAS: 546-89-4).
[Chemical Properties]

solid
[Uses]

Lithium acetate is used in the laboratory as buffer for gel electrophoresis of DNA and RNA. It has a lower electrical conductivity and can be run at higher speeds than can gels made from TAE buffer (5-30V/cm as compared to 5 - 10 V / cm). Lithium boric acid or sodium boric acid are usually preferable to lithium acetate or TAE when analyzing smaller fragments of DNA (less than 500 bp) due to the higher resolution of borate-based buffers in this size range as compared to acetate buffers.
Lithium acetate is also used to permeabilize the cell wall of yeast for use in DNA transformation. It is believed that the beneficial effect of LiAc is caused by its chaotropic effect denaturing both DNA, RNA and proteins.
[Definition]

ChEBI: An acetate salt comprising equal numbers of acetate and lithium ions.
[Flammability and Explosibility]

Nonflammable
[reaction suitability]

core: lithium
[Synthesis]

Lithium acetate can be obtained by reacting lithium carbonate with acetic acid: Li2CO3 + 2 CH3COOH → 2 CH3COOLi + H2O + CO2↑

Spectrum DetailBack Directory
[Spectrum Detail]

Lithium acetate(546-89-4)1HNMR
Lithium acetate(546-89-4)13CNMR
Lithium acetate(546-89-4)IR1
Lithium acetate(546-89-4)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Lithium acetate, pure(546-89-4)
[Sigma Aldrich]

546-89-4(sigmaaldrich)
[TCI AMERICA]

Lithium Acetate,>98.0%(T)(546-89-4)
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