| Identification | More | [Name]
(S)-(+)-Glycidyl butyrate | [CAS]
65031-96-1 | [Synonyms]
BUTYRIC ACID (S)-GLYCIDYL ESTER
(S)-2,3-EPOXY-1-PROPYL N-BUTYRATE
(S)-GLYCIDYL BUTANOATE
(S)-(-)-GLYCIDYL BUTYRATE
(S)-(+)-GLYCIDYL BUTYRATE
(S)-GLYCIDYL BUTYRATE
(S)-(+)-GLYCIDYL BUTYRATE , EE 98%
(S)-(+)-Glycidyl butyrate, 98%, ee 98%
[(2S)-Oxiran-2-yl]methyl butanoate | [Molecular Formula]
C7H12O3 | [MDL Number]
MFCD00273369 | [Molecular Weight]
144.17 | [MOL File]
65031-96-1.mol |
| Chemical Properties | Back Directory | [Appearance]
Colorless to light yellow liqui | [alpha ]
31 º (neat) | [Boiling point ]
90°C (19 mmHg) | [density ]
1.018 | [refractive index ]
1.428 | [Fp ]
185°F | [storage temp. ]
Storage temp. -20°C | [Specific Gravity]
1.018 | [Optical Rotation]
[α]21/D +31°, neat | [BRN ]
8198560 | [InChI]
1S/C7H12O3/c1-2-3-7(8)10-5-6-4-9-6/h6H,2-5H2,1H3/t6-/m0/s1 | [InChIKey]
YLNSNVGRSIOCEU-LURJTMIESA-N | [SMILES]
CCCC(=O)OC[C@@H]1CO1 | [CAS DataBase Reference]
65031-96-1(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H227-H302-H312-H315-H319-H335 | [Precautionary statements ]
P261-P305+P351+P338-P210e-P280-P405-P501a | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
2810 | [WGK Germany ]
3 | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29156000 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to light yellow liqui | [Uses]
(S)-Oxiranylmethyl Butyrate is the enantiomer of (2R)-2-Oxiranylmethyl Ester Butanoic Acid (O847090), which is a reagent used in the synthesis of glycidol, a stabilizer in manufacturing of vinyl polymers; intermediate in the synthesis of glycerol, glycidyl ethers, and amines; additive for oil and synthetic hydraulic fluids; epoxy resin diluent. | [Synthesis]
The enzymatic hydrolytic resolution of (±)-glycidyl butyrate using a lipase from Candida antarctica (fraction B) (CAL-B) has been performed. An appropriate reaction conditions permitted to obtain a quite pure (S)-(+)-Glycidyl butyrate using as biocatalyst the CAL-B immobilized on a support covered with polyethylenimine at 25 °C, pH 7 and 10% of dioxane (ee > 90% at 64% of conversion)[1]. | [References]
[1] Palomo, J. M., Segura, R. L., Fuentes, M., Ortiz, C. C., Guisán, J. M., & Fernández-Lafuente, R. (2006). Unusual enzymatic resolution of (±)-glycidyl-butyrate for the production of (S)-glycidyl derivatives. Enzyme and Microbial Technology, 38 3, Pages 429-435. https://doi.org/10.1016/j.enzmictec.2005.06.020
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