ChemicalBook--->CAS DataBase List--->65605-70-1

65605-70-1

65605-70-1 Structure

65605-70-1 Structure
IdentificationBack Directory
[Name]

Perfluoroalkylethyl acrylate
[CAS]

65605-70-1
[Synonyms]

Perfluoroalkylethyl acrylate
Perfluoroalkyl Ethyl Acrylates
PFAEA (Perfluoroalkylethylacrylate)
Perfluoroalkylethyl Acrylate Forfluo
1H,1H,2H,2H-Perfluoroalkyl-1-acrylate
1H,1H,2H,2H-Perfluoroalkyl-1-acrylates
2-(Perfluoroalkyl)Ethyl Acrylates, Mixture
Perfluoroalkylethyl acrylate ISO 9001:2015 REACH
Poly(difluoromethylene), α-fluoro-ω-[2- [(1-oxo-2-propenyl)oxy]ethyl]-
Poly(difluoroMethylene),a-fluoro-w-[2-[(1-oxo-2-propen-1-yl)oxy]ethyl]-
[EINECS(EC#)]

689-782-8
[Molecular Formula]

C9H7F9O2.(C2F4)n
[MOL File]

65605-70-1.mol
[Molecular Weight]

168.114
Chemical PropertiesBack Directory
[Melting point ]

-1 to 25 °C
[Boiling point ]

100 - 220 °C @ 10 mm Hg
[density ]

1.6 @ 25 °C
[refractive index ]

1.33 @ 25 °C
[Fp ]

> 110 °C
[Cosmetics Ingredients Functions]

NOT REPORTED
[InChI]

InChI=1S/C6H7F3O2/c1-2-5(10)11-4-3-6(7,8)9/h2H,1,3-4H2
[InChIKey]

NWBWGFFZPIVONT-UHFFFAOYSA-N
[SMILES]

C(OCCC(F)(F)F)(=O)C=C
[EPA Substance Registry System]

Poly(difluoromethylene), .alpha.-fluoro-.omega.-[2-[(1-oxo-2-propen-1-yl)oxy]ethyl]- (2-Propeonic acid, perfluoro-C6-14-alkylethyl esters, C8 rich) (65605-70-1)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H319
[Precautionary statements ]

P264-P280-P305+P351+P338-P337+P313P
Hazard InformationBack Directory
[Description]

Perfluoroalkylethyl acrylate is an important monomer for the synthesis of fluoropolymers, and is also a key step in the synthesis of fluorine-containing finishing agents.
[Uses]

Perfluoroalkylethyl acrylate is a polymer that can be used as an important monomer for the synthesis of fluoropolymers.
[Synthesis]

Using p-toluenesulfonic acid as catalyst, Perfluoroalkylethyl acrylate was synthesized.
Experimental procedure: Add polyfluoroalcohol, acrylic acid, and solvent to a dry four-necked flask equipped with a stirrer, reflux condenser, thermometer and water separator, and add p-toluenesulfonic acid after stirring evenly. The temperature is raised to reflux, and the reaction is carried out for a period of time until the water collected in the water separator reaches the theoretical amount. The solvent and excess acrylic acid were evaporated, and 5% (mass fraction) sodium bicarbonate solution was added dropwise to the cooled reaction solution until the pH was about 7-8. Filtration yielded a milky white solid. After vacuum drying, vacuum distillation was performed to collect Perfluoroalkylethyl acrylate at 82-134°C under 199.3Pa.
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