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140-88-5

140-88-5 Structure

140-88-5 Structure
IdentificationMore
[Name]

Ethyl acrylate
[CAS]

140-88-5
[Synonyms]

2-PROPENOIC ACID ETHYL ESTER
ACRYLIC ACID ETHYL ESTER
EA
ETHYL 2-PROPENOATE
ETHYL ACRYLATE
FEMA 2418
RARECHEM AL BI 0670
Acrylate d'ethyle
acrylated’ethyle
acrylated’ethyle(french)
Acrylic acid, ethyl ester (inhibited)
Akrylanem etylu
akrylanemetylu
Carboset 511
carboset511
CH2=CHCOOC2H5
Ethoxycarbonylethylene
Ethyl acrylate, inhibited
Ethyl ester of 2-propenoic acid
Ethyl propenoate
[EINECS(EC#)]

205-438-8
[Molecular Formula]

C5H8O2
[MDL Number]

MFCD00009188
[Molecular Weight]

100.12
[MOL File]

140-88-5.mol
Chemical PropertiesBack Directory
[Appearance]

colourless liquid
[Appearance]

Ethyl acrylate is a colorless liquid. Sharp, acrid odor. The Odor Threshold is 0.000240.0009 ppm
[mp ]

−71 °C(lit.)
[bp ]

99 °C(lit.)
[density ]

0.921 g/mL at 20 °C
[vapor density ]

3.5 (vs air)
[vapor pressure ]

31 mm Hg ( 20 °C)
[refractive index ]

n20/D 1.406(lit.)
[FEMA ]

2418
[Fp ]

60 °F
[storage temp. ]

Refrigerator
[Stability:]

Stable, but may polymerize upon exposure to light. Highly flammable. Keep cool. Incompatible with oxidizing agents, peroxides and other polymerization initiators.
[Water Solubility ]

1.5 g/100 mL (25 ºC)
[FreezingPoint ]

99.8℃
[Merck ]

14,3759
[BRN ]

773866
[Uses]

Ethyl Acrylate is a flavoring agent that is a clear, colorless liquid. its odor is fruity, harsh, penetrating, and lachrymatous (causes tears). it is sparingly soluble in water and miscible in alcohol and ether, and is obtained by chemical synthesis.
[Uses]

Monomer for acrylic resins.
[CAS DataBase Reference]

140-88-5(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Propenoic acid, ethyl ester(140-88-5)
[EPA Substance Registry System]

140-88-5(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F,Xn
[Risk Statements ]

R11:Highly Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R43:May cause sensitization by skin contact.
[Safety Statements ]

S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S33:Take precautionary measures against static discharges .
S36/37:Wear suitable protective clothing and gloves .
[RIDADR ]

UN 1917 3/PG 2
[WGK Germany ]

2
[RTECS ]

AT0700000
[F ]

8
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29161220
[Safety Profile]

Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion and inhalation. Moderately toxic by skin contact and intraperitoneal routes. Human systemic effects by inhalation: eye, olfactory, and pulmonary changes. A skin and eye irritant. Characterized in its terminal stages by dyspnea, cyanosis, and convulsive movements. It caused severe local irritation of the gastroenteric tract; and toxic degenerative changes of cardiac, hepatic, renal, and splenic tissues were observed. It gave no evidence of cumulative effects. When applied to the intact skin of rabbits, the ethyl ester caused marked local irritation, erythema, edema, thickening, and vascular damage. Animals subjected to a fairly high concentration of these esters suffered irritation of the mucous membranes of the eyes, nose, and mouth as well as lethargy, dpspnea, and convulsive movements. A substance that migrates to food from packagmg materials. Flammable liquid. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. Violent reaction with chlorosulfonic acid. To fight fire, use CO2, dry chemical, or alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
[Hazardous Substances Data]

140-88-5(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Etanol-->SULFURIC ACID-->Acrylonitrile-->CARBON MONOXIDE-->Acrylic acid-->Carbomer 940-->Acrylamide-->Acrolein-->2-Oxetanone-->ETHYLENE-->3-Hydroxypropionitrile-->Ammonium hydrogen sulfate-->Self-interlinkage adhesive T-->Ethyl 3-chloropropionate-->NICKEL CARBONYL
[Preparation Products]

Carbomer 940-->Enalapril-->Ethyl 5-[3-(4,6-dimethoxy pyrimidyl-2-yl)ureido]methylpyrazolyl-4-carboxylic ester-->Styrene-acrylic latex-->ETHYL 2-(BROMOMETHYL)ACRYLATE-->Ciprofloxacin hydrochloride-->ETHYL 4-PIPERIDONE-3-CARBOXYLATE HYDROCHLORIDE-->1-BENZYL-3-METHYL-4-PIPERIDONE-->2,3,4,5-Tetrahydro-5-methyl-1H-pyrido[4,3-b]indol-1-one-->5,6-DIHYDRO-4-(2-METHYL-2-PHENYLHYDRAZINO)-2-1H-PYRIDINONE-->4-Piperidinone-->carfentrazone-ethyl-->acrylic resin coating finish-->2,4-Piperadinedione-->3-AMINO-PROPIONIC ACID ETHYL ESTER-->impregnanting agent for leather-->Thickening agent-->Ethyl 3-(benzylamino)propanoate-->3-ISOPROPYLAMINO-PROPIONIC ACID ETHYL ESTER X HCL >98%-->Adhesive for electrostatic flocking-->Leather coating agent of filling acrylic resin-->Vinyl acetate-acrylate copolymer,emulsion-->Ethyl 3-methylthiopropionate
Hazard InformationBack Directory
[General Description]

A clear colorless liquid with an acrid odor. Flash point 60°F. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Auto ignition temperature 721°F (383°C) (NTP). Less dense than water. Vapors heavier than air. Used to make paints and plastics.
[Reactivity Profile]

A flammable liquid, confirmed carcinogen. ETHYL ACRYLATE, INHIBITED(140-88-5) can react vigorously with oxidizing reagents, peroxides,strong alkalis and polymerization initiators. [NTP] ETHYL ACRYLATE, INHIBITED(140-88-5) reacts violently with chlorosulfonic acid [Sax, 9th ed., 1996, p. 1515]. When an inhibited monomer was placed in a clear glass bottle exposed to sunlight, exothermic polymerization set in and caused the bottle to burst. The use of brown glass or metal containers and increase in inhibitor concentration (to 200 ppm; tenfold) was recommended [MCA Case History No. 1759]. ETHYL ACRYLATE, INHIBITED(140-88-5) may polymerize when exposed to light and ETHYL ACRYLATE, INHIBITED(140-88-5) is subject to slow hydrolysis. Inhibitors do not function in the absence of air. Solutions in DMSO are stable for 24 hours under normal lab conditions. [NTP].
[Air & Water Reactions]

Highly flammable. Insoluble in water.
[Hazard]

Toxic by ingestion, inhalation, skin absorption; irritant to skin and eyes. Flammable, dangerous fire and explosion hazard. Possible carcinogen.
[Health Hazard]

May cause irritation and burns of eyes and skin. Exposure to excessive vapor concentrations can also cause drowsiness accompanied by nausea, headache, or extreme irritation of the respiratory tract.
[Potential Exposure]

This material is used in emulsion polymers for paints, textiles, adhesives, coatings and binders; as a monomer in the manufacture of homopolymer and copolymer resins for the production of paints and plastic films
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
[Shipping]

UN1917 Ethyl acrylate, Hazard Class: 3; Labels: 3-Flammable liquid
[Incompatibilities]

May form explosive mixture with air. Atmospheric moisture and strong alkalies may cause fire and explosions unless properly inhibited (Note: Inert gas blanket not recommended). Heat, light or peroxides can cause polymerization. Incompatible with oxidizers (may be violent), peroxides, polymerizers, strong alkalis; moisture, chlorosulfonic acid, strong acids; amines. May accumulate static electrical charges, and may cause ignition of its vapors. Polymerizes readily unless an inhibitor, such as hydroquinone is added. Uninhibited vapors may plug vents by the formation of polymers.
[Waste Disposal]

Incineration or by absorption and landfill disposal
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

ethyl acrylate(140-88-5).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Ethyl acrylate(140-88-5)13CNMR
Ethyl acrylate(140-88-5)IR1
Ethyl acrylate(140-88-5)1HNMR
Ethyl acrylate(140-88-5)Raman
Ethyl acrylate(140-88-5)MS
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Ethyl acrylate, stabilized, 99.50%(140-88-5)
[Alfa Aesar]

Ethyl acrylate, 99%, stab. with ca 20ppm 4-methoxyphenol(140-88-5)
[Sigma Aldrich]

140-88-5(sigmaaldrich)
[TCI AMERICA]

Ethyl Acrylate  (stabilized with MEHQ),>99.0%(GC)(140-88-5)
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