| Identification | More | [Name]
2-Methoxybenzonitrile | [CAS]
6609-56-9 | [Synonyms]
2-CYANOANISOLE
2-METHOXYBENZONITRILE
AKOS 91422
AKOS B005792
O-CYANOANISOLE
O-METHOXYBENZONITRILE
1-Cyano-2-methoxybenzene
Benzonitrile, 2-methoxy-
o-Anisonitrile
2-Methoxybenzonitrile o-Methoxybenzonitrile
2-methoxybnezonitrile
Methyl 2-cyanophenyl ether | [EINECS(EC#)]
229-559-0 | [Molecular Formula]
C8H7NO | [MDL Number]
MFCD00001783 | [Molecular Weight]
133.15 | [MOL File]
6609-56-9.mol |
| Chemical Properties | Back Directory | [Melting point ]
24.5°C | [Boiling point ]
135 °C12 mm Hg(lit.)
| [density ]
1.093 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.5465(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [Water Solubility ]
Slightly soluble in water | [form ]
Liquid | [color ]
Clear colorless to pale yellow | [BRN ]
2207134 | [InChI]
InChI=1S/C8H7NO/c1-10-8-5-3-2-4-7(8)6-9/h2-5H,1H3 | [InChIKey]
FSTPMFASNVISBU-UHFFFAOYSA-N | [SMILES]
C(#N)C1=CC=CC=C1OC | [CAS DataBase Reference]
6609-56-9(CAS DataBase Reference) | [NIST Chemistry Reference]
o-Methoxybenzonitrile(6609-56-9) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
3276 | [WGK Germany ]
3
| [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29269090 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless liquid | [Uses]
2-Methoxybenzonitrile was used in the synthesis of 5-(4′-methyl [1,1′-biphenyl]-2-yl)-1H-tetrazole. | [Preparation]
o-Anisidine with sodium nitrite to make a diazonium salt solution, add it to the lead cyanide solution, and then add benzene. Put the mixture for 10-15h and carry out steam distillation, separate the benzene layer from the distillate, dry it with calcium chloride, evaporate the benzene, and distill the residue under reduced pressure, collect 120-122.5°C (1.2kPa fraction) to get 2-Methoxybenzonitrile, yield 64.5-67.3%. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 77, p. 109, 1955 DOI: 10.1021/ja01606a035
Synthesis, p. 641, 1992
Tetrahedron Letters, 32, p. 1007, 1991 DOI: 10.1016/S0040-4039(00)74473-X | [General Description]
Surface-enhanced Raman spectra study of 2-methoxybenzonitrile has been reported. |
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