677-69-0

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677-69-0 Structure

Identification	More
[Name] Heptafluoroisopropyl iodide
[CAS] 677-69-0
[Synonyms] 1,1,1,2,3,3,3-heptafluoro-2-iodo-propane 2-HEPTAFLUOROISOPROPYLIODIDE 2-IODOHEPTAFLUOROPROPANE 2-IODOPERFLUOROPROPANE HEPTAFLUORO-2-IODOPROPANE HEPTAFLUOROISOPROPYL IODIDE PERFLUORO-2-IODOPROPANE PERFLUOROISOPROPYL IODIDE 1,1,1,2,3,3,3-heptafluoro-2-iodo-propan Heptafluoroiodopropane Isoheptafluoropropyliodide Propane, heptafluoro-2-iodo- 2-Iodo-1,1,1,2,3,3,3-heptafluoropropane PERFLUORO-ISO-PROPYL IODIDE 98% 2-Iodoheptafluoropropane 98% 2-Iodoheptafluoropropane98% HEPTAFLUORO-2-IODOPROPANE , STABILIZED WITH COPPER Heptafluoro-2-iodopropane, 97%, stab. with copper powder Heptafluoro-2-iodopropane, 97%, stab. with copper 2-Iodoperfluoropropane, Heptafluoroisopropyl iodide, Perfluoroisopropyl iodide
[EINECS(EC#)] 211-643-3
[Molecular Formula] C3F7I
[MDL Number] MFCD00042089
[Molecular Weight] 295.93
[MOL File] 677-69-0.mol

Chemical Properties	Back Directory
[Appearance] clear colorless to yellowish liquid
[Melting point ] -58 °C
[Boiling point ] 40 °C (lit.)
[density ] 2.08 g/mL at 25 °C(lit.)
[vapor pressure ] 7.12 psi ( 20 °C)
[refractive index ] n20/D 1.329(lit.)
[Fp ] 38°C
[storage temp. ] Keep Cold
[form ] clear liquid
[color ] Colorless to Light yellow to Light red
[Specific Gravity] 2.10
[Water Solubility ] insoluble
[Sensitive ] Light Sensitive
[BRN ] 1841228
[Exposure limits] ACGIH: TWA 0.01 ppm
[InChI] 1S/C3F7I/c4-1(11,2(5,6)7)3(8,9)10
[InChIKey] BBZVTTKMXRPMHZ-UHFFFAOYSA-N
[SMILES] FC(F)(F)C(F)(I)C(F)(F)F
[LogP] 3.94
[CAS DataBase Reference] 677-69-0(CAS DataBase Reference)
[NIST Chemistry Reference] Propane, 1,1,1,2,3,3,3-heptafluoro-2-iodo-(677-69-0)
[EPA Substance Registry System] 677-69-0(EPA Substance)

Safety Data	Back Directory
[Hazard Codes ] Xn,Xi,T
[Risk Statements ] R20:Harmful by inhalation. R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ] S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ] 2810
[WGK Germany ] 3
[RTECS ] TZ3925000
[F ] 8
[Hazard Note ] Irritant
[TSCA ] T
[REACH Registrations] Active
[HazardClass ] 6.1(b)
[PackingGroup ] III
[HS Code ] 29037800
[Storage Class] 10 - Combustible liquids
[Hazard Classifications] Acute Tox. 4 Inhalation Eye Irrit. 2 Skin Irrit. 2 STOT SE 3

Material Safety Data Sheet(MSDS)	Back Directory
[msds information] 1,1,1,2,3,3,3-heptafluoro-2-iodo-propane(677-69-0).msds

Hazard Information	Back Directory
[Chemical Properties] clear colorless to yellowish liquid
[Uses] Heptafluoro-2-iodopropane may be used in the preparation of perfluoropropyl magnesium bromide and perfluoropropyl magnesium iodide. It may be used as chain-transfer agent in telomerization reactions of: 1,1-difluoroethylene and tetrafluoroethylene CF₃I, C₂F₅I and n-C₃F₇I with 1,1-difluoroethylene n-C₃F₇I with tetrafluoroethylene
[General Description] Heptafluoro-2-iodopropane is a secondary fluoro alkyl iodide. It can be prepared by addition of iodine monofluoride to hexafluoropropene.
[Flammability and Explosibility] Nonflammable
[Synthesis] 25 mL of experimental fluoropropane, 97 g of potassium iodide and 76 mL of water were placed in a reaction flask, and the reaction was stirred at 75 °C for 1 h. After cooling, 100 mL of ether was added, and the organic phase was washed once with 100 mL of
[Purification Methods] Purify it by gas chromatography on a triacetin (glyceryl triacetate) column, followed by bulb-to-bulb distillation at low temperature. Store it over Cu powder to stabilise it. UV has max at 271nm ( 240) in pet ether (b 60-80o). [Haszeldine J Chem Soc 1767, 3761 1953, Beilstein 1 III 255, 1 IV 225.]

Spectrum Detail	Back Directory
[Spectrum Detail] Heptafluoroisopropyl iodide(677-69-0)MS Heptafluoroisopropyl iodide(677-69-0)¹HNMR Heptafluoroisopropyl iodide(677-69-0)¹³CNMR Heptafluoroisopropyl iodide(677-69-0)IR1 Heptafluoroisopropyl iodide(677-69-0)Raman

Well-known Reagent Company Product Information	Back Directory
[Acros Organics] Heptafluoroisopropyl iodide, 99%(677-69-0)
[Alfa Aesar] Heptafluoro-2-iodopropane, 97%, stab. with copper powder(677-69-0)
[Sigma Aldrich] 677-69-0(sigmaaldrich)
[TCI AMERICA] Heptafluoroisopropyl Iodide,>98.0%(GC)(677-69-0)

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