| Identification | More | [Name]
Diethyl isopropylidenemalonate | [CAS]
6802-75-1 | [Synonyms]
2-ISOPROPYLIDENE-MALONIC ACID DIETHYL ESTER
DIETHYL 2-(1-METHYLETHYLIDENE)MALONATE
DIETHYL ISOPROPYLIDENEMALONATE
ISOPROPYLIDENEMALONIC ACID DIETHYL ESTER
Malonic acid, isopropylidene-, diethyl ester
Propanedioic acid, (1-methylethylidene)-, diethyl ester
Diethyl 2-isopropylidenepropandioate
1-Methylethylidenepropanedioic acid diethyl ester | [EINECS(EC#)]
229-876-4 | [Molecular Formula]
C10H16O4 | [MDL Number]
MFCD00009147 | [Molecular Weight]
200.23 | [MOL File]
6802-75-1.mol |
| Chemical Properties | Back Directory | [Melting point ]
93-94 °C | [Boiling point ]
175-178 °C/120 mmHg (lit.) | [density ]
1.021 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.451(lit.)
| [Fp ]
229 °F
| [storage temp. ]
Sealed in dry,2-8°C | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Specific Gravity]
1.021 | [λmax]
214nm(EtOH)(lit.) | [BRN ]
1776122 | [InChI]
1S/C10H16O4/c1-5-13-9(11)8(7(3)4)10(12)14-6-2/h5-6H2,1-4H3 | [InChIKey]
WEISAZNMMVPNTH-UHFFFAOYSA-N | [SMILES]
CCOC(=O)\C(=C(/C)C)C(=O)OCC | [CAS DataBase Reference]
6802-75-1(CAS DataBase Reference) | [NIST Chemistry Reference]
Diethyl isopropylidenemalonate(6802-75-1) |
| Safety Data | Back Directory | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [HS Code ]
29171900 | [Storage Class]
10 - Combustible liquids |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless liquid | [Uses]
Diethyl isopropylidenemalonate has been used in the synthesis of retinoids having functional groups at the side-chain terminus. | [General Description]
Reduction of diethyl isopropylidenemalonate with sodium borohydride has been reported. |
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